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The correct order of the thermal stabili...

The correct order of the thermal stability of hydrogen halides `(H-X)` is

A

`HlgtHbegtHClgtHF`

B

`HFgtHClgtHBrgtHI`

C

`HClltHFltHBrltHI`

D

`HIgtHClgtHFltHBr`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of thermal stability of hydrogen halides (H-X), we need to analyze the bond strength of the H-X bonds. The thermal stability of these compounds is influenced by the strength of the bond between hydrogen and the halogen (X). ### Step-by-Step Solution: 1. **Understanding Thermal Stability**: - Thermal stability refers to the ability of a compound to resist decomposition at elevated temperatures. For hydrogen halides, this stability is primarily determined by the strength of the H-X bond. 2. **Bond Strength and Bond Length**: - The strength of the H-X bond is inversely related to the bond length. A shorter bond length typically indicates a stronger bond. Conversely, a longer bond length indicates a weaker bond. 3. **Analyzing the Halogens**: - The halogens (F, Cl, Br, I) increase in size as we move down the group in the periodic table: - Fluorine (F) is the smallest, followed by chlorine (Cl), bromine (Br), and iodine (I), which is the largest. 4. **Bond Length Trends**: - As the size of the halogen increases, the bond length of the H-X bond also increases: - H-F < H-Cl < H-Br < H-I - This means that H-I has the longest bond length and therefore the weakest bond strength. 5. **Bond Strength Trends**: - Since bond strength decreases with increasing bond length, we can establish the following order of bond strengths: - H-F > H-Cl > H-Br > H-I 6. **Thermal Stability Order**: - Since thermal stability is directly related to bond strength, the order of thermal stability for hydrogen halides is: - H-F > H-Cl > H-Br > H-I ### Final Answer: The correct order of thermal stability of hydrogen halides (H-X) is: **H-F > H-Cl > H-Br > H-I**

To determine the correct order of thermal stability of hydrogen halides (H-X), we need to analyze the bond strength of the H-X bonds. The thermal stability of these compounds is influenced by the strength of the bond between hydrogen and the halogen (X). ### Step-by-Step Solution: 1. **Understanding Thermal Stability**: - Thermal stability refers to the ability of a compound to resist decomposition at elevated temperatures. For hydrogen halides, this stability is primarily determined by the strength of the H-X bond. 2. **Bond Strength and Bond Length**: ...
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