Home
Class 12
CHEMISTRY
Asseration: The abnormality in b.pt. of ...

Asseration: The abnormality in `b.pt.` of `NH_(3)` in hydrides of `N-`family is due to `H-`bonding.
Reason: The boiling point of hydrides of `N-`family shows the order: `NH_(3)gtBiH_(3)gtSbH_(3)gtAsH_(3)gtPH_(3)`.

A

If both asseration and reson are true and the reason is the correct explanation of the asseration.

B

If both asseration and reason are true ans the reason is the correct explanation of the asseration.

C

If asseration is true but reason is false.

D

If asseration is false but reason is true.

Text Solution

Verified by Experts

The correct Answer is:
C

The b.pt. order is
`{:underset(290)(BiH_(3))gtunderset(254)(SbH_(3))gtunderset(238.5)(NH_(3))gtunderset(210)(AsH_(3))gtunderset(185.5 K)(PH_(3)):}`
Promotional Banner

Topper's Solved these Questions

  • P BLOCK ELEMENTS ( GROUP 15,16,17,18)

    A2Z|Exercise AIPMT/NEET Questions|71 Videos
  • P BLOCK ELEMENTS ( GROUP 15,16,17,18)

    A2Z|Exercise AIIMS Questions|25 Videos
  • P BLOCK ELEMENTS ( GROUP 15,16,17,18)

    A2Z|Exercise General Properties And Fluorides Of Xenon (Group 18)|44 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • SOLID STATE

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

Basic strength order NH_(3) gtPH_(3) gtAsH_(3) gtBiH_(3) .

N_(2)+3H_(2) to NH_(3)

The decreasing order of melting points is NH_(3) gt (CH_(3))_(3) N gtPH_(3) .

Arrange the following in decreasing order of solubility in water: (CH_(3))_(3)N, (CH_(3))_(2)NH, CH_(3)NH_(2)

The decreasing order of the boiling points of the following hydrides (i) NH_3 (ii) PH_3 (iii) AsH_3 (iv) SbH_3 (v) H_2O is

A2Z-P BLOCK ELEMENTS ( GROUP 15,16,17,18)-Section B - Assertion Reasoning
  1. Asseration: lowest oxidation number of N-family is -3 and highest oxid...

    Text Solution

    |

  2. Asseration: Nitrogen forms H(2)N-NH(2),N(2) and N(3)^(-) ions whereas ...

    Text Solution

    |

  3. Asseration: The abnormality in b.pt. of NH(3) in hydrides of N-family ...

    Text Solution

    |

  4. Asseration: The halogens develop+ve charge on N-atom and thus more +ve...

    Text Solution

    |

  5. Asseration: N in NO(2) and nitrolic acid has +4 and +3 oxidation numb...

    Text Solution

    |

  6. Asseration: Number of P-O-P bonds in cyclotrimetaphosphoric acid is 3....

    Text Solution

    |

  7. Asseration: NH(3) and PH(3) differ from each other in their reaction w...

    Text Solution

    |

  8. Asseration: The elctronic structure of O(3) is: Reason: structur...

    Text Solution

    |

  9. Assertion: Superoxide ion is paramagnetic whereas peroxide ion is diam...

    Text Solution

    |

  10. Assertion: Both are dibasic and permonosulphuric acid does not exit in...

    Text Solution

    |

  11. Asseration: The thermal stability of hydrides of oxygen family decreas...

    Text Solution

    |

  12. Asseration: Number of S-S bonds in H(2)S(n)O(6) is (n-1). Reason: H(...

    Text Solution

    |

  13. Asseration: 3SnCl(2)+6HCl+O(3)rarr3SnCl(4)+3H(2)O is possible reaction...

    Text Solution

    |

  14. Asserarion:Bleaching action action of SO(2) is temporary and by reduct...

    Text Solution

    |

  15. Asseration: Cyclic trimer of SO(3) possesses have six membered hetero-...

    Text Solution

    |

  16. Assertion: F atom has less negative electron gain enthaply than Ci ato...

    Text Solution

    |

  17. Asseration: F-F bond in F(2) molecule is strong. Reason: F-atom is s...

    Text Solution

    |

  18. Asseration: HF forms two series of salts but HCl not. Reason: F-atom...

    Text Solution

    |

  19. Asseration: Iodine does not displace Cl(2) or Br(2) from their chlorid...

    Text Solution

    |

  20. Asseration: A fresh stain of iodine is washed with hypo solution. Reas...

    Text Solution

    |