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What will be the charge on Fe^(x +) if t...

What will be the charge on `Fe^(x +)` if the megnetic moment is `sqrt(24)` ?

A

`+ 2`

B

`+ 3`

C

Zero

D

None of these

Text Solution

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The correct Answer is:
To determine the charge on \( \text{Fe}^{(x +)} \) given that the magnetic moment is \( \sqrt{24} \), we can follow these steps: ### Step 1: Use the formula for magnetic moment The magnetic moment (\( \mu \)) is given by the formula: \[ \mu = \sqrt{n(n + 2)} \] where \( n \) is the number of unpaired electrons. ### Step 2: Set up the equation Given that the magnetic moment is \( \sqrt{24} \), we can set up the equation: \[ \sqrt{24} = \sqrt{n(n + 2)} \] ### Step 3: Square both sides Squaring both sides to eliminate the square root gives: \[ 24 = n(n + 2) \] ### Step 4: Rearrange the equation Rearranging the equation, we have: \[ n^2 + 2n - 24 = 0 \] ### Step 5: Solve the quadratic equation Now, we can solve this quadratic equation using the quadratic formula: \[ n = \frac{-b \pm \sqrt{b^2 - 4ac}}{2a} \] where \( a = 1, b = 2, c = -24 \). Calculating the discriminant: \[ b^2 - 4ac = 2^2 - 4 \cdot 1 \cdot (-24) = 4 + 96 = 100 \] Now substituting back into the formula: \[ n = \frac{-2 \pm \sqrt{100}}{2 \cdot 1} = \frac{-2 \pm 10}{2} \] This gives us two potential solutions: \[ n = \frac{8}{2} = 4 \quad \text{and} \quad n = \frac{-12}{2} = -6 \] Since \( n \) must be a non-negative integer, we take \( n = 4 \). ### Step 6: Determine the electronic configuration of iron The atomic number of iron (Fe) is 26, and its electron configuration in the ground state is: \[ \text{Fe}: [\text{Ar}] 3d^6 4s^2 \] Given that there are 4 unpaired electrons, we need to find the oxidation state of iron that results in this configuration. ### Step 7: Find the oxidation state When iron loses electrons to form cations, the 4s electrons are lost first, followed by the 3d electrons. If we assume that the oxidation state is \( +2 \), the configuration would be: \[ \text{Fe}^{2+}: [\text{Ar}] 3d^6 \] This configuration has 4 unpaired electrons, which matches our earlier calculation. ### Conclusion Thus, the charge on \( \text{Fe}^{(x +)} \) is: \[ x = +2 \]

To determine the charge on \( \text{Fe}^{(x +)} \) given that the magnetic moment is \( \sqrt{24} \), we can follow these steps: ### Step 1: Use the formula for magnetic moment The magnetic moment (\( \mu \)) is given by the formula: \[ \mu = \sqrt{n(n + 2)} \] where \( n \) is the number of unpaired electrons. ...
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A2Z-THE D AND F BLOCK ELEMENTS-Section D - Chapter End Test
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