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What is the co-ordination number of the ...

What is the co-ordination number of the metal in `[Co(en)_2Cl_2]^+`?

A

(a) `4`

B

(b) `5`

C

(c) `6`

D

(d) `3`

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The correct Answer is:
To determine the coordination number of the metal in the complex ion \([Co(en)_2Cl_2]^+\), follow these steps: ### Step 1: Identify the central metal atom The central metal atom in the complex is cobalt (Co). ### Step 2: Identify the ligands The ligands attached to the cobalt are: - \(en\) (ethylenediamine), which is a bidentate ligand. - \(Cl^-\) (chloride), which is a monodentate ligand. ### Step 3: Count the number of donor atoms from ligands - Each \(en\) ligand can donate 2 pairs of electrons (2 donor atoms). - Since there are 2 \(en\) ligands, they contribute: \[ 2 \, \text{(from first } en\text{)} + 2 \, \text{(from second } en\text{)} = 4 \, \text{donor atoms} \] - The \(Cl^-\) ligands contribute 1 donor atom each. Since there are 2 \(Cl^-\) ligands, they contribute: \[ 1 \, \text{(from first } Cl\text{)} + 1 \, \text{(from second } Cl\text{)} = 2 \, \text{donor atoms} \] ### Step 4: Calculate the total coordination number Now, add the donor atoms from both types of ligands: \[ 4 \, \text{(from } en\text{)} + 2 \, \text{(from } Cl\text{)} = 6 \] ### Conclusion The coordination number of the cobalt in the complex \([Co(en)_2Cl_2]^+\) is **6**. ---

To determine the coordination number of the metal in the complex ion \([Co(en)_2Cl_2]^+\), follow these steps: ### Step 1: Identify the central metal atom The central metal atom in the complex is cobalt (Co). ### Step 2: Identify the ligands The ligands attached to the cobalt are: - \(en\) (ethylenediamine), which is a bidentate ligand. ...
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A2Z-COORDINATION COMPOUNDS-Section D - Chapter End Test
  1. What is the co-ordination number of the metal in [Co(en)2Cl2]^+?

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  2. Co-ordination number of Fe in the complexes [Fe(CN)6]^(4-), [Fe(CN)6]^...

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  3. (Me)(2) SiCl(2) on hydrolysis will produce.

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  4. Types of isomerism shown by [Cr(NH3)5NO2]Cl2 is

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  5. Which of the following will no give a precipate with AgNO3?

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  6. In the process of extraction of gold, Roasted gold ore +CN^(-)+H2Oov...

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  7. A reagent used for identifying nickel ion is:

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  8. Which of the following complex is an outer orbital complex?

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  9. Which of the following has the largest number of isomers? .

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  10. Which kind of isomerism is exhibited by octahedral [Co(NH(3))(4)Br(2)]...

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  11. Which one of the following is expected to exhibit optical isomerism (e...

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  12. The pair of the compounds in which both the metals are in the highest ...

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  13. IUPAC name of [Co(NH3)5NO2]Cl2

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  14. Which of the following is considered to be an anticancer species ?

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  15. An aqueous solution of COCL2 on addition of excess of concentrated HCl...

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  16. The correct order for the wavelength of absorption in the visible regi...

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  17. In which of the following pairs both the complex show optical isomeris...

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  18. Which of the following compounds shows optical isomerism?

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  19. CN^(-) is a strong field ligand. This is due to the fact that

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  20. Considering H2O as a weak field ligand, the number of unpaired electro...

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  21. Given the molecular formula of the hexacoordinated complexes (A) [CoCl...

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