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The d- electron configurations of Mn^(2+...

The d- electron configurations of `Mn^(2+),Fe^(2+),Co^(3+)` and `Ni^(2+)` ard `3d^(5),3d^(6),3d^(6),3d^(8)` , respectively
Which of the following aqua complexes will exhibit the minimum paramagnetic behviour ? .

A

(a) `[Fe(H_2O)_6]^(2+)`

B

(b) `[Ni(H_2O)_6]^(2+)`

C

(c) `[Cr(H_2O)_6]^(2+)`

D

(d) `[Mn(H_2O)_6]^(2+)`

Text Solution

Verified by Experts

The correct Answer is:
B

`Cr^(2+), Mn^(2+), Fe^(2+)` and `Ni^(2+)` have 4, 5, 4 and 2 unpaired electrons respectively.
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A2Z-COORDINATION COMPOUNDS-AIPMT/NEET Questions
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  2. [Co(NH2)2]Cl exhibits

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  3. The d- electron configurations of Mn^(2+),Fe^(2+),Co^(3+) and Ni^(2+) ...

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  4. Which of the following will give a pair of enantiomorphs? .

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  7. Which of the following complexes is not expected to exhibit isomerism?

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  8. [Co(NH3)4Cl2]^(+) exhibits

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  9. Which of the following complex ion(s) is/are not expected to absorb vi...

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  10. Which of the following does not have optical isomer?

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  11. Crystal field stabilization energy for high spin d^4 octahedral comple...

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  12. Which of the following complex ion is not expected to absorb visible l...

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  13. The complex, [Pt(py)(NH3)BrCl] will have how many geometrical isomers?

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  14. [Co(HN(3))(6)][Cr(CN)(6)] and [Cr(NH(3))(6)][Co(CN)(6)] are .

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  15. The d-electron configurations of Cr^(2+), Mn^(2+), Fe^(2+) and Co^(2+)...

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  16. Of the following complex ions, which is diamagnetic in natures?

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  18. Low spin complex of d^6-cation in an octahedral field will have the fo...

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  19. A magnetic moment of 1.73 B.M. will be shown by one among the followin...

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