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[Co(HN(3))(6)][Cr(CN)(6)] and [Cr(NH(3))...

`[Co(HN_(3))_(6)][Cr(CN)_(6)]` and `[Cr(NH_(3))_(6)][Co(CN)_(6)]` are .

A

(a) Geometrical isomerism

B

(b) Linkage isomerism

C

(c) Ionization isomerism

D

(d) Coordination isomerism

Text Solution

Verified by Experts

The correct Answer is:
D

Coordination sphere is interchanged.
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Which isomerism is exhibited by [Co(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(6)][Co(CN)_(6)] ?

The complexes [Co(NH_(3))_(6)][C(CN)_(6)] and [Cr(NH_(3))_(6)][Co(CN)_(6)] are the examples of which type of isomerism ?

How can be the following pair of isomers be distinguished from one another I [Co(NH_(3))_(6)][Cr(NO_(2))_(6)] and (II) [Cr(NH_(3))_(6)][Co(No_(2))_(6)] I [Cr(NH_(3))_(6)[Cr(No_(2))_(6)] and (II) [Cr(NH_(3))_(4)(No_(2))_(2)][Cr(NH_(3))_(2)(NO_(2))_(4)] .

Name the type of isomerism exibited by the following isomers : (1) [Cr(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(4)(CN)_(2)][Cr(NH_(3))_(2)(CN)_(4)] (2) [Co(py)_(2)(H_(2)O)_(2)Cl_(2)]Cl and [Co(py)_(2)(H_(2)O)Cl_(3)]H_(2)O (3) [Pt(NH_(3))_(4)Br_(2)]Cl_(2) and [Pt(NH_(3))_(4)Cl_(2)]Br_(2) (4) [Co(NH_(3))_(5)NO_(2)]Cl_(2) and [Co(NH_(3))_(5)ONO]Cl_(2)

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