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The d-electron configurations of Cr^(2+)...

The d-electron configurations of `Cr^(2+), Mn^(2+), Fe^(2+)` and `Co^(2+)` are `d^4, d^5, d^6` and `d^7` respectively. Which one of the following will exhibit minimum paramagnetic behavious?

A

(a) `[Cr(H_2O)_6]^(2+)`

B

(b) `[Mn(H_2O)_6]^(2+)`

C

(c) `[Fe(H_2O)_6]^(2+)`

D

(d) `[Co(H_2O)_6]^(2+)`

Text Solution

Verified by Experts

The correct Answer is:
D

`H_2O` is weak field ligand, thus `CO^(2+)` has only 3 unpaired electrons.
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