Home
Class 12
CHEMISTRY
Which of these statements about [Co(CN)6...

Which of these statements about `[Co(CN)_6]^(3-)` is true?

A

(a) `[Co(CN)_6]^(3-)` has four unpaired electrons and will be in a high-spin configuration

B

(b) `[Co(CN)_6]^(3-)` has no unpaired electrons and will be in a high-spin configuration

C

(c) `[Co(CN)_6]^(3-)` has no unpaired electrons and will be in a low-spin configuration

D

(d) `[Co(CN)_6]^(3-)` has four unpaired electrons and will be in a low-spin configuration

Text Solution

Verified by Experts

The correct Answer is:
C

`[Co(CN)_6]^(3-)`, oxidation no. of `Co=+3`, `Co^(3+)=3d^6`
As `CN^(-)` is a strong field ligand, so all electrons will be paired up and complex will be low spin complex.
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    A2Z|Exercise AIIMS Questions|17 Videos
  • COORDINATION COMPOUNDS

    A2Z|Exercise Assertion-Reasoning Questions|5 Videos
  • COORDINATION COMPOUNDS

    A2Z|Exercise Section B - Assertion Reasoning|15 Videos
  • CHEMICAL KINETICS

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • ELECTROCHEMISTRY

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

Which of these statements is true about chara?

Which one of the following statements about CH_(3)CN is not true?

Which of these statements about the partial pressure of CO_(2) is true ?

Which of these statement about bryophytes is true?

Which of the following statements about muscle is true?

A2Z-COORDINATION COMPOUNDS-AIPMT/NEET Questions
  1. Which one of the following is an outer orbital complex and exhibits pa...

    Text Solution

    |

  2. Low spin complex of d^6-cation in an octahedral field will have the fo...

    Text Solution

    |

  3. A magnetic moment of 1.73 B.M. will be shown by one among the followin...

    Text Solution

    |

  4. An excess of AgNO3 is added to 100mL of a 0.01M solution of dichlorote...

    Text Solution

    |

  5. Among the following complexes, the one which shows zero crystal field ...

    Text Solution

    |

  6. The complex used as an anticancer agent is

    Text Solution

    |

  7. Cobalt (III) chloride forms several octahedral complexes with amonia. ...

    Text Solution

    |

  8. Which of these statements about [Co(CN)6]^(3-) is true?

    Text Solution

    |

  9. The IUPAC name of the coordination compound K3[Fe(CN)6] is:

    Text Solution

    |

  10. Both [Ni(CO)4] and [Ni (CN)4]^(2-) are diamagnetic The hybridisation...

    Text Solution

    |

  11. The sum of coordination number and oxidation number of the metal M in ...

    Text Solution

    |

  12. What is the co-ordination number of the metal in [Co(en)2Cl2]^+?

    Text Solution

    |

  13. Which of the following has longest C-O bond length? (Free C-O bond len...

    Text Solution

    |

  14. An example of a sigma bonded organometallic compound is:

    Text Solution

    |

  15. The correct order of the stoichiometries of AgCl formed when AgNO3 in ...

    Text Solution

    |

  16. Correct increasing order for the wavelengths of absorption in the visi...

    Text Solution

    |

  17. Pick out the correct statement with respect to [Mn(CN)(6)]^(3-):

    Text Solution

    |

  18. The type of isomersim shown by the complex [CoCl(2) (en)(2)] is

    Text Solution

    |

  19. The geometry and magnetic behaviour of the complex [Ni(CO)4] are

    Text Solution

    |

  20. Iron carbonyl, Fe(CO)5 is

    Text Solution

    |