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In the process of extraction of gold, ...

In the process of extraction of gold,
Roasted gold ore `+CN^(-)+H_2Ooverset(o_2)rarr[X]+OH^(-)`
`[X]+Znrarr[Y]+Au`
Identify the complexes [X] and [Y]

A

(a) `X=[Au(CN)_2]^(-), Y=[Zn(CN)_4]^(2-)`

B

(b) `X=[Au(CN)_4]^(3-), Y=[Zn(CN)_4]^(2-)`

C

(c) `X=[Au(CN)_2]^(-), Y=[Zn(CN)_6]^(4-)`

D

(d) `X=[Au(CN)_4]^(-), Y=[Zn(CN)_4]^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
A

Roasted gold are `+CN^(-)+H_2Ooverset(O_2)rarr[Au(CN)_2]^(-)+OH`
`[Au(CN)_2]^(-)+Znrarr[Zn(CN)_4]^(2-)`.
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