Home
Class 12
CHEMISTRY
Consider the following reactions which a...

Consider the following reactions which are carried out at the same temperature
`CH_(3) -Br + OH^Theta overset(EtOH)rarr CH_(3) -OH + BrQ ...(i)`
` CH_(3) Br + OH^Theta overset(DMSO)rarr CH_(3) -OH + BrQ ...(ii)`
Which of the following statement is correct about these reactions

A

Both the reactions take place at the same rate

B

The first reaction takes place faster than second reaction .

C

The second reaction takes place faster than first reaction .

D

Both the reactions take place by `S_(N)1` mechanism .

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the reactions provided and determine the correct statement regarding their rates, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactions**: - The first reaction is: \[ CH_3Br + OH^- \overset{(EtOH)}{\rightarrow} CH_3OH + Br^- \] - The second reaction is: \[ CH_3Br + OH^- \overset{(DMSO)}{\rightarrow} CH_3OH + Br^- \] 2. **Understand the Solvents**: - The first reaction uses ethanol (EtOH), which is a polar protic solvent. - The second reaction uses dimethyl sulfoxide (DMSO), which is a polar aprotic solvent. 3. **Determine the Mechanism**: - In polar protic solvents like ethanol, the nucleophile (OH^-) is solvated, which can slow down the reaction rate. - In polar aprotic solvents like DMSO, the nucleophile is less solvated, allowing it to be more reactive and thus facilitating a faster reaction. 4. **Compare the Reaction Rates**: - Since DMSO is a polar aprotic solvent, it enhances the nucleophilicity of OH^-, leading to a faster reaction compared to the reaction in ethanol. - Therefore, the reaction in DMSO (reaction ii) will proceed faster than the reaction in ethanol (reaction i). 5. **Conclusion**: - The correct statement is that the second reaction (in DMSO) is faster than the first reaction (in ethanol). ### Final Answer: The second reaction (using DMSO) is faster than the first reaction (using ethanol). ---

To analyze the reactions provided and determine the correct statement regarding their rates, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactions**: - The first reaction is: \[ CH_3Br + OH^- \overset{(EtOH)}{\rightarrow} CH_3OH + Br^- ...
Promotional Banner

Topper's Solved these Questions

  • ORGANIC COMPOUNDS CONTAINING HALOGENS

    A2Z|Exercise Elimination Reaction And Polyhalogen Compounds|67 Videos
  • ORGANIC COMPOUNDS CONTAINING HALOGENS

    A2Z|Exercise Methods Of Preparationof Haloarenes|19 Videos
  • ORGANIC COMPOUNDS CONTAINING HALOGENS

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • MOCK TEST

    A2Z|Exercise Mock Test 2|45 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

State the role of reagents shown on arrows in the following chemical reactions. CH_(3)CH_(2)OH overset(KMnO_(4))rarr CH_(3)COOH

Consider the following reaction CH_3-CH=CH_2overset(Br_2//NaCl)rarr Product of the reaction will be

The reation CH_(3)CH_(2)Br+overset(-)OHrarrCH_(3)CH_(2)OH+Br^(-) is an example of

Consider the following reaction, CH_(3)Br+OH^(-)rarrCH_(3)OH+Br^(-) The true statement about the above process is

Consider the following sequence of reactions ltbRgt CH_(3)CH(OH)CH_(3)overset(NaH)(rarr)Aoverset(CH_(3)CH_(2)I)(rarr)B The product (B) is

Consider the following reaction: CH_(3)-overset(O)overset(||)(C)-OH+CH_(3)-OH overset(H^(o+))hArrCH_(3)-overset(O)overset(||)(C)-O-CH_(3)+HOH True about the reaction is:

A2Z-ORGANIC COMPOUNDS CONTAINING HALOGENS-Physical Properties And Nuleophilic Substitution Reaction
  1. When ethyl iodide is heated with silver nitrate the product obtained i...

    Text Solution

    |

  2. For a given alkyl group the densities of the halides follow the order

    Text Solution

    |

  3. Identify the major product

    Text Solution

    |

  4. HEATING ALKYL HALIDES WITH DRY SILVER OXIDE

    Text Solution

    |

  5. Alkyl halide can be converted into alkene by

    Text Solution

    |

  6. Among the following, the molecule with the highest dipole moment is :

    Text Solution

    |

  7. The increasing order of reactivity of the following isomeric halides w...

    Text Solution

    |

  8. Consider the following reactions which are carried out at the same tem...

    Text Solution

    |

  9. Which of the follwing is the example of S(N)2 reaction .

    Text Solution

    |

  10. Teriary alkyl halides are practically inert to S(N)2 mechanism becaus...

    Text Solution

    |

  11. The structure of the major product formed in the following reaction ...

    Text Solution

    |

  12. A solution of (-l)- chloro -1 phenyletane in toluene recemises slowly ...

    Text Solution

    |

  13. The order of reactivities of the following alky halides for an S(N)2 r...

    Text Solution

    |

  14. The following compound on hydrolysis in equeous acetone will give .

    Text Solution

    |

  15. The major product of the following reaction is .

    Text Solution

    |

  16. KI in acetone, undergoes S(N)2 reaction with each of P,Q ,R and S The ...

    Text Solution

    |

  17. CH(3) -underset(C(3)H(7)(n))underset(|)overset(C(2)H(5))overset(|)C-CI...

    Text Solution

    |

  18. What is the product of the following S(N)2 reaction ? .

    Text Solution

    |

  19. Which is the correct reaction coordinate diagram for the following sol...

    Text Solution

    |

  20. Rate limiting S(N)1 followingthe sequence The statement about sequence...

    Text Solution

    |