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An alcohol contains 60% carbon and 13.3%...

An alcohol contains `60%` carbon and `13.3%` hydrogen and givens positive idoform test. The alcohol is

A

`2-`propanol

B

`1-`propanol

C

`2-`butanol

D

`1-`butanol

Text Solution

Verified by Experts

The correct Answer is:
A

`C:H:O = (60)/(12):(13.3)/(1):(26.7)/(16) = (5)/(1.67):(13.3)/(1.67):(1.67)/(1.67) = 3:8:1`
The formula of the compound is `CH_(3)H_(8)O`.
Since the alcohol gives positive iodoform test. It has `CH_(3)-underset(H)underset(|)overset(|)C-OH`, hence it is `2`-propanol.
`(underset(OH)underset(|)(CH_(3)CHCH_(3)))`
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