Home
Class 12
CHEMISTRY
The calcohol which easily reacts with co...

The calcohol which easily reacts with conc. `HCI` is

A

`CH_(3)-CHOH-CH_(2)-CH_(3)`

B

`CH_(3)-CH_(2)-CH_(2)-CH_(2)-OH`

C

`(CH_(3))_(3)-C-OH`

D

`(CH_(3))_(3)-CH-CH_(2)OH`

Text Solution

Verified by Experts

The correct Answer is:
C

Tertiary alcohol readily reacts with halogen acid
`CH_(3)rarroverset(CH_(3))overset(darr)underset(CH_(3))underset(uarr)C-OHrarrCH_(3)rarroverset(CH_(3))overset(|)underset(CH_(3))underset(|)(C^(+))+OH^(-)`
Presence of `3` alky`1` group increases electron density on `3^(@)` carbon atom. Hence`-OH` group is easily removed. After the removal of `-OH` group `3^(@)` carbonium ion is fromed which is most stable
Promotional Banner

Topper's Solved these Questions

  • ALCOHOLS, PHENOLS AND ETHERS

    A2Z|Exercise Phenols|53 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    A2Z|Exercise Ethers|34 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACID

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

The reagent which easily reacts with ethanol and propanol is

Aniline reacts with conc. HNO_(3) to give

Out of (a) CH_(2)=CH-CH_(2)OH (b) CH_(2)=CH-CH_(2)-CH_(2)-OH , which will react more easily with conc. HCl in the presence of anhydrous ZnCl_(2) ?

Which of the following species is formed when ethanamines is reacted with conc. HCI ?

Carbon reacts with conc. H_(2)SO_(4) to gives

A2Z-ALCOHOLS, PHENOLS AND ETHERS-Chemical Properties Of Alcohols
  1. The compound 'A' when trated with ceric ammonium nitrate solution give...

    Text Solution

    |

  2. The-OH group of Methyl alcohol cannot be replaced by chlorine by the t...

    Text Solution

    |

  3. The calcohol which easily reacts with conc. HCI is

    Text Solution

    |

  4. Which of the following compounds is oxidised to prepare Methyl Ethyl k...

    Text Solution

    |

  5. In the esterification reaction of alcohols

    Text Solution

    |

  6. When primary alcohol is oxidised with chlorine, it produces

    Text Solution

    |

  7. Which of the following compound given yellow precipiate with I(2) and ...

    Text Solution

    |

  8. Which of the following react with benzoic acid to form enthy1 benzoate...

    Text Solution

    |

  9. If there be a compound of the formula CH(3)C(OH) which one of the foll...

    Text Solution

    |

  10. The dehydration of 2-Methyl butanol with conc. H(2)SO(4) gives

    Text Solution

    |

  11. Aoverset(Cu)underset(Delta)rarrCH(3)CH(2)OHoverset(Al(2)O(3))underset(...

    Text Solution

    |

  12. The best method to prepare cyclohexene form cyclohexanol is by using

    Text Solution

    |

  13. Tertiary buthy1 alcohl gives tertiary buty1 chloride on treatement wit...

    Text Solution

    |

  14. Among the following compounds which can be dehydrated very easily is:

    Text Solution

    |

  15. Phenyl magesoium bromide reacts with methanol to give:

    Text Solution

    |

  16. Among the following the one that gives pistive idoform test upon react...

    Text Solution

    |

  17. In the following sequence of reactions: CH(3)CH(2)OHoverset(P+I(2))...

    Text Solution

    |

  18. The main product of the following reaction is C(6)H(5)CH(2)CH(OH)CH(...

    Text Solution

    |

  19. An unknown alcohol is treated with the 'Lucas reagent' to determine wh...

    Text Solution

    |

  20. In the given transformation which of the following is the most appropr...

    Text Solution

    |