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An organic compound X on treatement with...

An organic compound `X` on treatement with acidified `K_(2)Cr_(2)O_(7)` gives a compound `Y` which reats with `I_(2)` and sodium carbonate to form tri-iodomethane. The compound `X` is

A

`CH_(3)OH`

B

`CH_(3)-CO-CH_(3)`

C

`CH_(3)CHO`

D

`CH_(3)CH(OH)CH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
D

`CH_(3)-underset(OH)underset(|)(CH)-CH_(3)overset(K_(2)Cr_(2)O_(7))underset(H_(2)SO_(4))rarrCH_(3)-underset(O)underset(||)(C)-CH_(3)`
`overset(NaOH)underset(I_(2))rarrunderset("Yellow ppt")(CHI_(3)) +CH_(3)COONa`
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