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When phenol reactes with CHCl(3) and Na...

When phenol reactes with `CHCl_(3)` and NaOH followed by acidification, salicyladehyde is obtained. Which of the following species are involed in the above-mentioned reaction as intermediates ?

A

B

C

D

Text Solution

Verified by Experts

The correct Answer is:
D

Riemer-Tiemann reaction involves electrophilic substitution on the hogly reactive phenoxide ring.
`HC CI_(3) +OH^(-) rarr H_(2)O^(-) :C CI_(3)`
`:barC CI_(3)rarrCI^(-) underset("sextet of electrons")underset("C has only a")( :C CI_(2))`
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When phenol is reactes with CHCI_(3) and NaOH followed by acidification, salicyladehyde is obtained. Which of the following species are involed in the above-mentioned reaction as intermediates ?

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