Home
Class 12
CHEMISTRY
Ortho -nitrophenol is less soluble in wa...

Ortho -nitrophenol is less soluble in water than `p`-and `m-`nitrophenols because

A

o-rth-bitriphenol is less soluble in water than p- and m-nitrophenol is more volatile steam than those of m- and p-isomers.

B

0-nitrophenol shows intramolecular H-bonding

C

0-nitrophenol shows intramolecular H-bonding

D

melting point of 0-nitrophenol is lower than those of m-and p-isomers

Text Solution

Verified by Experts

The correct Answer is:
B

There is intramolecular H-bonding in o-nitrophenol and thus solubility in water is decreased.
intramoleuclar H-bonding
Promotional Banner

Topper's Solved these Questions

  • MOCK TEST

    A2Z|Exercise Assertion-Reasoning|5 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF METALS

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • ORGANIC COMPOUNDS CONTAINING HALOGENS

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

Assertion (A) o-nitrophenol is less soluble in water than the m and p-isomers. Reason (R) m and p-nitrophenols exist as associated molecules.

Lif is less soluble in water than KF because

LiF is less soluble in water than KF because

Select the correct option : S_(1) : Catechol is less acidic than resorcinol. S_(2) : Ortho - nitrophenol is less acidic than para - nitrophenol. S_(3) : Ortho- cresol is less acidic than its meta and para isomers. S_(4) : Generally ortho substituted phenols are less acidic than their coressponding meta & para isomers.

The boiling point of para nitrophenol is greater than that of ortho nitrophenol, because

A2Z-MOCK TEST-Mock Test 2
  1. Select the incorrect statement for a dry cell:

    Text Solution

    |

  2. The rate constatnt of a second order reaction is 10^(-2) "mol"^(-1) l...

    Text Solution

    |

  3. Which statement about enzymes is not corect ?

    Text Solution

    |

  4. Formic acid is obtained when :

    Text Solution

    |

  5. Whin (NH4)2SO4 are heated, we get :

    Text Solution

    |

  6. The destruction of the biological bature and activity of proteins by h...

    Text Solution

    |

  7. The weakest interparticle forces are present in :

    Text Solution

    |

  8. Cerium (Z= 58) is an important nember of the lanthanoids . Which of th...

    Text Solution

    |

  9. One mole of complex compound Co(NH3)5Cl3 gives 3 moles of ions on diss...

    Text Solution

    |

  10. Consider the reaction, Cl(2)(aq) + H(2)S(aq) rarr S(s) + 2H^(+) (aq)...

    Text Solution

    |

  11. The molality of a urea solution in which 0.0100 g of urea, [(NH(2))...

    Text Solution

    |

  12. Consider the acidity of the carboxylic acids: (1) PhCOOH (2) o-NO(...

    Text Solution

    |

  13. Ortho -nitrophenol is less soluble in water than p-and m-nitrophenols ...

    Text Solution

    |

  14. The compound formed on heation cholrobenzed with cholral in presence ...

    Text Solution

    |

  15. For the complete combustion of ethanol, C(2)H(5)OH(l)+3O(2)(g)rarr2CO(...

    Text Solution

    |

  16. For the Daniell cell Zn| Zn^(2+) || Cu^(2+) | Cu with The questions c...

    Text Solution

    |

  17. Assertion: A catalyst is more effective in finely divided form. Reas...

    Text Solution

    |

  18. For the Daniell cell Zn| Zn^(2+) || Cu^(2+) | Cu with The questions c...

    Text Solution

    |

  19. For the Daniell cell Zn| Zn^(2+) || Cu^(2+) | Cu with The questions c...

    Text Solution

    |

  20. For the Daniell cell Zn| Zn^(2+) || Cu^(2+) | Cu with The questions c...

    Text Solution

    |