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The correct order of decreasing C-O bond...

The correct order of decreasing `C-O` bond length of (1) `CO,(II)CO_(3)^(2-) (III)CO_(2)` is .

A

`CO_(3)^(2-) lt CO_(2) lt CO`

B

`CO_(2) lt CO_(3)^(2-) lt CO`

C

`CO lt CO_(3)^(2-) lt CO_(2) `

D

` CO lt CO_(2) lt CO_(3)^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
d

B O in CO i.e. `overset(-)(C) = overset(+)(O)`: is 3, that of `C = C = O` is 2 while that of `CO_(3)^(2-)` ion is 1.33. since the bond length increases as the bond order decrease, i.e. `CO lt CO_(2) lt CO_(3)^(2-)`. Thus option (d) is correct.
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