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(CH(3))(3)-C-MgCl on reaction with D(2)O...

`(CH_(3))_(3)-C-MgCl` on reaction with `D_(2)O` produces

A

`(CH_(3))_(3)CD`

B

`(CH_(3))_(3)COD`

C

`(CD_(3))_(3)CD`

D

`(CD_(3))_(3)COD`

Text Solution

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The correct Answer is:
A
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(CH_(3))_(3)CMgBr on reaction with D_(2)O produces :

Me_3 C-MgCl on reaction with D_2 O produces :

(CH_3)_3CMgCl on reaction with D_2O produces

Identify the total number of following compounds which liberate CH_(4) gas on reaction with CH_(3)MgCl (i) H_(2)O (ii) CH_(2)=CH_(2) (iii) Me-C-=C-H

Which S_(N)1 reaction would you expect to take place more rapidly ? (a) (i) (CH_(3))_(3)C Cl+H_(2)O to (CH_(3))_(3)COH+HCl Or (ii) (CH_(3))_(3)C Br+H_(2)O to (CH_(3))_(3)COH+HBr (b) (i) (CH_(3))_(3)C Cl+H_(2)O to (CH_(3))_(3)COH + HCl Or (ii) C_(5)H_(5)Cl+H_(2)O to C_(5)H_(5)OH + HCl (c) (i) (CH_(3))_(3)C Cl+ H_(2)O to (CH_(3))_(3)COH + HCl Or (ii) (CH_(3))_(3)C Cl+ CH_(3)OH to (CH_(3))_(3)COCH_(3)+ HCl (d) (i) (CH_(3))_(3)C Cl(1.0M)+CH_(3)CH_(2)O^(-)(1.0M) overset(C_(2)H_(2)OH)to (CH_(3))_(3)COCH_(2)CH_(3)+Cl^(-) Or (ii) (CH_(3))_(3)C Cl(1.0M)+CH_(3)CH_(2)O^(-)(2.0M) overset(C_(2)H_(2)OH)to (CH_(3))_(3)COCH_(2)CH_(3)+Cl^(-)

A2Z-HYDROCARBONS-Section D - Chapter End Test
  1. (CH(3))(3)-C-MgCl on reaction with D(2)O produces

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  2. Anti- Markovwnikoff's addtion of HBr is not observed in

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  3. Which of the following reactions will yield 2,2-dibromopropane ?

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  4. The products formed by the ozonolysis - hydrolysis of compound of form...

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  5. When acetylen reacted with hydroxylic acid in presence of HgCl(20 the ...

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  6. When propyne reacts with aqueous H(2)SO(4) in the presence of HgSO(4)...

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  7. Which one of the following does not dissolve in conc. H(2)SO(4)?

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  8. Which one of the following compounds will give in the presence of pero...

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  9. Which of the following alkene in acid catalysed hydration form 2-methy...

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  10. Which of the following compounds yields only one product on monobromin...

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  11. Aqueous solution of the following compounds are electrolysed . Acetyle...

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  12. Dehydration of butan -2-ol with conc. H(2)SO(4) gives preferred produc...

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  13. CH(3)-C-=C-CH(3)overset(NaNH(2))rarr'X'. What is X ?

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  14. Identify the compound 'Y' in the following sequency of reaction HC-=...

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  15. Dehydration of 1-butanol gives 2-butene as a major product , by which ...

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  16. The prinicipal organic product formed is the reaction : CH(2)=CH(CH(...

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  17. Which of the following decolorizes Potassium permanganate?

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  18. CH(3)C-=C CH(3) overset((i)X) underset((ii)H(2)O //Zn)rarr X in the...

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  19. Which of the following is Friedel - Craft's reaction

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  20. Condition for maximum yield of C(2)H(5)Cl is

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  21. When ethyl alcohol is heated with red phosphorus and HI, then which o...

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