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(CH(3))(3)COH+CH(3)MgBr rarr Hydrocarbon...

`(CH_(3))_(3)COH+CH_(3)MgBr rarr` Hydrocarbon `(A),(A)` is

A

(a) `(CH_(3))_(3)C C H_(3)`

B

(b) `(CH_(3))_(3)CH`

C

(c) `CH_(4)`

D

(d) none of these

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The correct Answer is:
To solve the given reaction `(CH₃)₃COH + CH₃MgBr`, we need to analyze the interaction between the alcohol and the Grignard reagent. Here’s a step-by-step breakdown of the reaction: ### Step 1: Identify the Reactants The reactants are: - **Tert-butyl alcohol**: `(CH₃)₃COH` - **Methylmagnesium bromide**: `CH₃MgBr` ### Step 2: Understand the Reaction Grignard reagents (like `CH₃MgBr`) are strong nucleophiles and react with electrophiles. In this case, the alcohol `(CH₃)₃COH` will react with the Grignard reagent. ### Step 3: Reaction Mechanism 1. The hydroxyl group (-OH) in tert-butyl alcohol is acidic. The Grignard reagent will deprotonate the alcohol, leading to the formation of tert-butoxide ion `(CH₃)₃CO⁻`. 2. The methyl group from the Grignard reagent will bond with the oxygen of the tert-butoxide ion. ### Step 4: Products Formation The reaction can be summarized as follows: - The hydrogen from the hydroxyl group of tert-butyl alcohol is replaced by the methyl group from the Grignard reagent. - This results in the formation of methane (CH₄) and tert-butyl methyl ether `(CH₃)₃COCH₃`. ### Step 5: Write the Final Products The final products of the reaction are: - **Methane (CH₄)** - **Tert-butyl methyl ether**: `(CH₃)₃COCH₃` ### Conclusion Thus, the hydrocarbon `(A)` formed in the reaction is **methane (CH₄)**. ### Final Answer: The hydrocarbon `(A)` is **CH₄ (methane)**. ---

To solve the given reaction `(CH₃)₃COH + CH₃MgBr`, we need to analyze the interaction between the alcohol and the Grignard reagent. Here’s a step-by-step breakdown of the reaction: ### Step 1: Identify the Reactants The reactants are: - **Tert-butyl alcohol**: `(CH₃)₃COH` - **Methylmagnesium bromide**: `CH₃MgBr` ### Step 2: Understand the Reaction ...
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(CH_3)_3COH+CH_3MgBr to hydrocarbon (A), (A) is

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CH_(3) - C -= N + CH_(3)MgBr rarr A

CH_(3)CH_(3)+HNO_(3)overset(675K)rarr

(CH_(3))_(3)CH+C Cl_(4)underset(Delta)overset((CH_(3))_(3)C-O-O-C(CH_(3))_(3))rarr The compound formed in the reaction is (i) (CH_(3))_(3)COH (ii) (CH_(3))_(3)C Cl (iii) CHCl_(3) (iv) C Cl_(4)

For the following reaction: (CH_(3))_(3)"CCl"+H_(2)O rarr (CH_(3))_(3)COH+HCl,((dx)/(dt))=k [(CH_(3))_(3)"CCl"] hence , rate determining step can be:

Which S_(N)1 reaction would you expect to take place more rapidly ? (a) (i) (CH_(3))_(3)C Cl+H_(2)O to (CH_(3))_(3)COH+HCl Or (ii) (CH_(3))_(3)C Br+H_(2)O to (CH_(3))_(3)COH+HBr (b) (i) (CH_(3))_(3)C Cl+H_(2)O to (CH_(3))_(3)COH + HCl Or (ii) C_(5)H_(5)Cl+H_(2)O to C_(5)H_(5)OH + HCl (c) (i) (CH_(3))_(3)C Cl+ H_(2)O to (CH_(3))_(3)COH + HCl Or (ii) (CH_(3))_(3)C Cl+ CH_(3)OH to (CH_(3))_(3)COCH_(3)+ HCl (d) (i) (CH_(3))_(3)C Cl(1.0M)+CH_(3)CH_(2)O^(-)(1.0M) overset(C_(2)H_(2)OH)to (CH_(3))_(3)COCH_(2)CH_(3)+Cl^(-) Or (ii) (CH_(3))_(3)C Cl(1.0M)+CH_(3)CH_(2)O^(-)(2.0M) overset(C_(2)H_(2)OH)to (CH_(3))_(3)COCH_(2)CH_(3)+Cl^(-)

A2Z-HYDROCARBONS-Section D - Chapter End Test
  1. (CH(3))(3)COH+CH(3)MgBr rarr Hydrocarbon (A),(A) is

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  2. Anti- Markovwnikoff's addtion of HBr is not observed in

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  3. Which of the following reactions will yield 2,2-dibromopropane ?

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  4. The products formed by the ozonolysis - hydrolysis of compound of form...

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  5. When acetylen reacted with hydroxylic acid in presence of HgCl(20 the ...

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  6. When propyne reacts with aqueous H(2)SO(4) in the presence of HgSO(4)...

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  7. Which one of the following does not dissolve in conc. H(2)SO(4)?

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  8. Which one of the following compounds will give in the presence of pero...

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  9. Which of the following alkene in acid catalysed hydration form 2-methy...

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  10. Which of the following compounds yields only one product on monobromin...

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  11. Aqueous solution of the following compounds are electrolysed . Acetyle...

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  12. Dehydration of butan -2-ol with conc. H(2)SO(4) gives preferred produc...

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  13. CH(3)-C-=C-CH(3)overset(NaNH(2))rarr'X'. What is X ?

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  14. Identify the compound 'Y' in the following sequency of reaction HC-=...

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  15. Dehydration of 1-butanol gives 2-butene as a major product , by which ...

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  16. The prinicipal organic product formed is the reaction : CH(2)=CH(CH(...

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  17. Which of the following decolorizes Potassium permanganate?

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  18. CH(3)C-=C CH(3) overset((i)X) underset((ii)H(2)O //Zn)rarr X in the...

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  19. Which of the following is Friedel - Craft's reaction

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  20. Condition for maximum yield of C(2)H(5)Cl is

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  21. When ethyl alcohol is heated with red phosphorus and HI, then which o...

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