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CH-=C-COOHoverset(HgSO(4) // H(2)SOH(4))...

`CH-=C-COOHoverset(HgSO_(4) // H_(2)SOH_(4))rarr` product `(A)` is

A

`CH_(2)=underset(OH)underset(|)(C )-COOH`

B

`CH_(3)-underset(O)underset(||)(C )-COOH`

C

`OHC-CH_(2)-COOH`

D

`OH-CH=CH-COOH`

Text Solution

Verified by Experts

The correct Answer is:
C

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CH_3-C-=CH overset(HgSO_4, H_2SO_4)to Major product is :

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HC-=CHoverset(HgSO_(4)//H_(2)SO_(4))rarr[A]overset("Oxidation")rarr[B]overset(PCl_(5))rarr[C]overset(H_(2))underset(Pd//BaSO_(4))rarr[D]underset(H_(3)O^(+))overset(CH_(3)MgBr)rarr[E]

I CH_(2)=C=CH_(2) overset (H_(3)O^(+)) rarr II CH_(3)C-=CH overset (H_(2)SO_(4) // HgSO_(4)) rarr III CH_(3)C-= CH overset(BH_(3) . THF ) underset (H_(2)O_(2) //OH) rarr Acetone is the major product in :

The major product (Y) in the following reactions is: CH_(3)-overset(CH_(3))overset(|)CH-C-=CH overset(HgSO_(4),H_(2)SO_(4))underset(H_(2)O)toX overset((i)C_(2)H_(5)MgBr,H_(2)O)underset((ii)"Conc",H_(2)SO_(4)//Delta)toY

The end product of the following reaction CHequivCHoverset(CH_(3)MgBr)rarroverset(CO_(2)"/"H_(3)O^(+))rarroverset(H_(2)O)underset(HgSO_(4)//H_(2)SO_(4))rarroverset(Ag_(2)O)underset("heat")rarroverset("heat")rarr is

The final product formed in the reaction C_(6)H_(5)C-=CHunderset(HgSO_(4))overset(H_(2)SO_(4))rarrA overset(NH_(2)OH)rarr B underset(2H_(3)O+)overset(1.LiAIH_(4))rarrC is .

What will be the final product (B) in the given reaction ? HCequivCHoverset(HgSO_(4)//H_(2)SO_(4))to(A)overset([O])to(B)

A2Z-HYDROCARBONS-Method of Preparation of Alkynes
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