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For which of these reactions will there ...

For which of these reactions will there be `Delta S` positive?

A

`H_(2)O_((g)) rarr H_(2)O_((l))`

B

`H_(2)+I_(2) rarr 2HI`

C

`CaCO_(3(s)) rarr CaO_((s))+CO_(2(g))`

D

`N_(2(g))+3H_(2(g)) rarr 2NH_(3(g))`

Text Solution

Verified by Experts

The correct Answer is:
C

In (a) `g gt l`, in (b) np=nr, in (d) `np lt nr`, in (c ) `s rarr g`. Hence entropy increases.
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MARVEL PUBLICATION-CHEMICAL THERMODYNAMICS AND ENERGETICS-MULTIPLE CHOICE QUESTIONS (Gibbs Free Energy)
  1. The occurrence of a reaction is impossible if

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  2. For a reaction to be spontaneous at all temperatures

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  3. For which of these reactions will there be Delta S positive?

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  4. Free enegry , G = H - TS, is state function that indicates whther a re...

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  5. Which of the following is true fo the reacion H(2)O(l)hArr H(2)O(g) at...

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  6. For a system in equilibrium, DeltaG=0, under conditions of constant

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  7. Since the enthalpy of elements in their natural state is taken to be z...

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  8. At constant T and P which of the following statement is correct for th...

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  9. A chemical reaction will be spontaneous if it is accompanied by a decr...

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  10. The standard Gibb's free energy change, DeltaG^(@) is related to equil...

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  11. Mark the correct statement.

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  12. One mole ofan ideal gas is allowed to expand freely and adiabatically ...

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  13. According to the second law of thermodynamics, a process (reaction) is...

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  14. Mechanical work is specially important in systems that contain

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  15. The favourable conditions for a spontaneous reaction are

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  16. Free enegry , G = H - TS, is state function that indicates whther a re...

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  17. The enthalpy of vaporization of a substance is 840 J per mol and its b...

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  18. If the enthalpy of vaporisation of water is 186.5 J mol^(-1), then ent...

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  19. If 900J//g of heat is exchanged at boiling point of water then water...

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  20. Two moles of ideal gas at 27^(@)C temperature is expanded reversibly f...

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