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The complex ions [Co(NH(3))(5)(NO(2))]^(...

The complex ions `[Co(NH_(3))_(5)(NO_(2))]^(2+)` and `[Co(NH_(3))_(5)(ONO)]^(2+)` are called

A

Linkage isomers

B

Ionisation isomers

C

Co-ordination isomers

D

Geometrical isomers

Text Solution

Verified by Experts

The correct Answer is:
A
Linkage isomerism.
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Write the type of isomerism exhibited by [Co(NH_(3))_(5)(NO_(2))]^(2+) and [Co(NH_(3))_(5)ONO]^(2+) pair of complex ion.

[Co(NH_(3))_(5)NO_(2)]Cl_(2) and [Co(NH_(3))_(5)ONO]Cl_(2) are related to each other as :

[Co(NH_(3))_(5)NO_(2)]SO_(4) shows

Which one of the following pairs of isomers ad ytpes of isomerism are correctly mathced? (i) [ Co(NH_(3))_(5)(NO_(2))]Cl_(2) and [Co(NH_(3))_(5)(ONO)]Cl_(2) . . . (Linkage) (ii) [Cu(NH_(3))_(4)][PtCl_(4)] and [Pt(NH_(3))_(4)][CuCl_(4)] . .. (coordination) (iii) [PtCl_(2)(NH_(3))_(4)]Br_(2) and [PtBr_(2)(NH_(3))_(4)]Cl_(2) . . (Ionization) Select the correct answer using the codes given below:

IUPAC name [Co(NH_(3))_(5)(NO_(2))]Cl_(2) is

MARVEL PUBLICATION-CO-ORDINATION COMPOUNDS-TEST YOUR GRASP
  1. The complex ions [Co(NH(3))(5)(NO(2))]^(2+) and [Co(NH(3))(5)(ONO)]^(2...

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  2. Which of the following is odd one out ?

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  3. An example for a double salt is

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  4. CuSO(4) dissolves in NH(3) due to formation of

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  5. K(4)[Fe(CN)(6)] is a

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  6. Some salts although containing two different metallic elements give te...

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  7. The EAN of iron in [Fe(CN)(6)]^(3-) is

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  8. Coordination number of Ni in [Ni(C2O4)3]^(4-) is:

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  9. According to Lewis the ligands are

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  10. According to the postulates of Werner for cooedination compounds

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  11. In[Co(NH(3))(6)]Cl(3),the number of covalent bonds is

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  12. Chemical formula for in iron(III) hexacyanoferrate(II) is

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  13. IUPAC name of Na(3)[Co(NO(2))(6)] is

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  14. Ligands in a complex salt are:

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  15. The IUPAC name of K(3)[Ir(C(2)O(4))(3)] is

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  16. In [Cr(C(2)O(4))(3)]^(3-), the isorerism shown is

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  17. Which of the following complex will show geometrical as well as optica...

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  18. A coordination compound of cobalt has the molecular, formula containin...

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  19. The number of isomers exhibited by [Cr(NH(3))(3)Cl(3)] is

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  20. Which of the following will give maximum number of isomer ?

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  21. The compounds [PtCl(2)(CH(3))(4)]Br(2) and [PtBr(2)(NH(3))(4)]Cl(2) co...

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