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A complex involving dsp^(2) hybridisatio...

A complex involving `dsp^(2)` hybridisation has

A

Square planar geometry

B

A tetrahedral geometry

C

An octahedral geometry

D

Trigonal planar geometry

Text Solution

Verified by Experts

The correct Answer is:
A

Bonding in co-ordination compounds.
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S-1: The [Co(o x)_(3)]^(3-) complex is diamagnetic andgains stability through chelation. S-2: The [Co(NO_(2))_(6)]^(4) is inner orbital complex involving d^(2)sp^(3) hybridisation and is paramagnetic. S-3: The complex [PtCl_(4)]^(2-) is square planar and is diamagnetic.

dsp^(2) hybridisation is found in

The d - orbital involved in dsp^(2) hybridisation si d_(x^(2)-y^(2)) .

dsp^(2) hybridization represent

The concept of hybridisation has been introduced to explain the shapes of molecules. It involves the intermixing of two or more atomic orbitals belonging to same atom but in or more atomic orbitals beloging to sasme atom but in different sub-shells so as to intermix and redistibute energies to from equivalent orbitals called hybrid orbitals.Depending upon toh enumber and nature of the orbitals involved, the hybridisation may be divided into sp (linear), sp^(2) (trigonal), sp^(3) (tetrahedral), sp^(3)d (trigonal bipyramidal), sp^(3)d^(3) (octahedral) and sp^(3)d^(3) (pentagonal bipyramidal) types. it may be noted that the orbitals of isolated atoms never hybridise and they do so at the time of bond formation. The d-orbital involved in dsp^(2) hybridisation is: