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The compound which reacts fastest with L...

The compound which reacts fastest with Lucas reagent at room temperature is

A

butan-1-ol

B

butan-2-ol

C

2-methylpropan-1-ol

D

2-methylpropane-2-ol

Text Solution

Verified by Experts

The correct Answer is:
D

By Lucas reagent test we can distinguish between primary , secondary and tertiary alcohols. On reaction with Lucas reagent (Conc. `HCl+` anhy. `ZnCl_2`) at room temperature , tert. alcohol `(2^(@))` give turbidity in 5-10 minutes , primary alcohols `(1^(@))` do not form a turbidity , i.e, the order of reactivity is ` 3^(@) gt 2^(@) gt 1^(@)`. 2-Methylpropan-2-ol is a tertiary alcohol and will react fastest .
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