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When acetaldehyde reacts with ammonia, t...

When acetaldehyde reacts with ammonia, the product is

A

hexamethylene tetramine

B

acetaldehyde ammonia

C

deacetone amine

D

ethyl amine

Text Solution

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The correct Answer is:
To determine the product of the reaction between acetaldehyde (CH₃CHO) and ammonia (NH₃), we can follow these steps: ### Step 1: Identify the Reactants The reactants are acetaldehyde (CH₃CHO) and ammonia (NH₃). Acetaldehyde contains a carbonyl group (C=O) which is reactive towards nucleophiles, and ammonia has a lone pair of electrons on nitrogen. ### Step 2: Nucleophilic Attack Ammonia acts as a nucleophile and attacks the electrophilic carbon atom of the carbonyl group in acetaldehyde. This leads to the formation of a tetrahedral intermediate. **Intermediate Structure:** - The carbonyl carbon becomes a tetrahedral carbon. - The nitrogen from ammonia is now bonded to the carbon, and the oxygen has a negative charge. ### Step 3: Proton Transfer In the tetrahedral intermediate, the negatively charged oxygen can deprotonate the positively charged nitrogen (which has gained a proton from ammonia). This results in the formation of an intermediate with an alcohol (OH) and an amine (NH₂) group. **Intermediate Structure:** - The structure now has a hydroxyl group (OH) and an amino group (NH₂) attached to the same carbon. ### Step 4: Elimination of Water The next step involves the elimination of a water molecule (H₂O) from the intermediate. This leads to the formation of an imine (C=N) bond. **Product Structure:** - The resulting product after the elimination of water is an imine, specifically acetaldehyde ammonia (CH₃CH=NH). ### Step 5: Final Product The final product of the reaction between acetaldehyde and ammonia is an imine, which can be represented as: - **Product:** CH₃CH=NH (acetaldehyde ammonia) ### Conclusion When acetaldehyde reacts with ammonia, the product formed is acetaldehyde ammonia (an imine). ---

To determine the product of the reaction between acetaldehyde (CH₃CHO) and ammonia (NH₃), we can follow these steps: ### Step 1: Identify the Reactants The reactants are acetaldehyde (CH₃CHO) and ammonia (NH₃). Acetaldehyde contains a carbonyl group (C=O) which is reactive towards nucleophiles, and ammonia has a lone pair of electrons on nitrogen. ### Step 2: Nucleophilic Attack Ammonia acts as a nucleophile and attacks the electrophilic carbon atom of the carbonyl group in acetaldehyde. This leads to the formation of a tetrahedral intermediate. ...
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