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The Grignard reagent required to prepare...

The Grignard reagent required to prepare 2-butanol from acetaldehyde is

A

`CH_(3)MgBr`

B

`CH_(3)overset(CH_(3))overset(|)(C)HMgBr`

C

`CH_(3)CH_(2)MgBr`

D

`CH_(3)MgCl`

Text Solution

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The correct Answer is:
To determine the Grignard reagent required to prepare 2-butanol from acetaldehyde, we can follow these steps: ### Step 1: Identify the structure of acetaldehyde Acetaldehyde has the chemical formula \( \text{C}_2\text{H}_4\text{O} \) and its structure can be represented as: \[ \text{CH}_3\text{CHO} \] This means it has a methyl group (\( \text{CH}_3 \)) attached to a carbonyl group (aldehyde). ### Step 2: Determine the target product, 2-butanol 2-butanol has the chemical formula \( \text{C}_4\text{H}_{10}\text{O} \) and its structure is: \[ \text{CH}_3\text{CH(OH)}\text{CH}_2\text{CH}_3 \] This indicates that 2-butanol has a hydroxyl group (\( \text{OH} \)) on the second carbon of a four-carbon chain. ### Step 3: Understand the reaction mechanism The Grignard reagent is generally represented as \( \text{R-MgX} \), where \( \text{R} \) is an alkyl or aryl group, \( \text{Mg} \) is magnesium, and \( \text{X} \) is a halogen (like Cl, Br, or I). In this case, we need to add a carbon chain to the acetaldehyde to form 2-butanol. ### Step 4: Determine the appropriate Grignard reagent To convert acetaldehyde to 2-butanol, we need to add a two-carbon chain to the carbonyl carbon of acetaldehyde. The appropriate Grignard reagent would be ethyl magnesium bromide (\( \text{C}_2\text{H}_5\text{MgBr} \)), which can be represented as: \[ \text{C}_2\text{H}_5\text{MgX} \] Here, \( \text{R} \) is \( \text{C}_2\text{H}_5 \) (ethyl group). ### Step 5: Write the overall reaction When ethyl magnesium bromide reacts with acetaldehyde, the nucleophilic ethyl group attacks the carbonyl carbon of acetaldehyde, leading to the formation of an intermediate alcohol, which upon hydrolysis yields 2-butanol: \[ \text{CH}_3\text{CHO} + \text{C}_2\text{H}_5\text{MgBr} \rightarrow \text{CH}_3\text{CH(OH)}\text{CH}_2\text{CH}_3 + \text{Mg(OH)Br} \] ### Conclusion Thus, the Grignard reagent required to prepare 2-butanol from acetaldehyde is: \[ \text{C}_2\text{H}_5\text{MgX} \]

To determine the Grignard reagent required to prepare 2-butanol from acetaldehyde, we can follow these steps: ### Step 1: Identify the structure of acetaldehyde Acetaldehyde has the chemical formula \( \text{C}_2\text{H}_4\text{O} \) and its structure can be represented as: \[ \text{CH}_3\text{CHO} \] This means it has a methyl group (\( \text{CH}_3 \)) attached to a carbonyl group (aldehyde). ...
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MARVEL PUBLICATION-ALDEHYDES,KETONES AND CARBOXYLIC ACIDS-CARBOXYLIC ACIDS
  1. The Grignard reagent required to prepare 2-butanol from acetaldehyde i...

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  2. In the case of carboxylic acids,the alpha-carbon is the carbon:

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  3. General formula for mono-carboxylic acid is :

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  4. Aliphatic carboxylic acid are functional isomers of

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  5. Compound having molecular formula C(3)H(6)O(2) is:-

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  6. Which of the following formula represent chloroethanoic acid ?

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  7. Fatty acids are

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  8. General formula for mono-carboxylic acid is :

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  9. Which of the following is example of tricarboxylic acid ?

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  10. Glacial acetic acid is the same as :

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  11. Which of the follwong compound does not have a carboxyl group.

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  12. Acetic acid is a weak acid because :

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  13. Which one of the following is ethanoic acid ?

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  14. The common name of CH(3)(CH(2))(16)COOH acid is :

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  15. The I.U.P.A.C. name of CH(3)-CH(2)-underset(CH(3))underset(|)(C)H-CH(2...

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  16. The I.U.P.A.C. name of lactic acid CH(3)CHOHCOOH is :

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  17. The IUPAC name of the compound :

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  18. Which of the following acids occur in ants ?

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  19. Most of the carboxylic acids exists as dimer in

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  20. Acetic acid can be separated from aqeous solution of acetic acid,at wh...

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  21. Which of the following is isobutyric acid?

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