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A compound containing molecular formula `C_(5)H_(10)Cl_(2)` on hydrolysis gives compound containing molecular formula `C_(5)H_(10)O`, which reacts with `NH_(2)OH` and also forms iodoform but does not give Fehling test original compound is

A

`CH_(3)-underset(Cl)underset(|)overset(Cl)overset(|)(C)-CH_(2)-CH_(2)-CH_(3)`

B

`CH_(3)-CH_(2)-underset(Cl)underset(|)overset(Cl)overset(|)(C)-CH_(2)-CH_(3)`

C

`CH_(3)-CH_(2)-CH_(2)-CH_(2)-underset(Cl)underset(|)overset(Cl)overset(|)(C)H`

D

`CH_(3)-underset(Cl)underset(|)(C)H-underset(Cl)underset(|)(C)-CH_(2)-CH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
A
`CH_(3)-underset(Cl)underset(|)overset(Cl)overset(|)(C) - CH_(2)-CH_(2)-CH_(3)underset(KOH)overset(Aq.)(rarr)underset("(Pentan-2-one)")(CH_(3)-overset(O)overset(||)(C)-CH_(2)CH_(2)CH_(3))`
Pentan-2-one ( methyl ketone )gives iodoform test and it reacts with `NH_(2)OH`. It does not give Fehling test.
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MARVEL PUBLICATION-ALDEHYDES,KETONES AND CARBOXYLIC ACIDS-CARBOXYLIC ACIDS
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  2. In the case of carboxylic acids,the alpha-carbon is the carbon:

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  3. General formula for mono-carboxylic acid is :

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  4. Aliphatic carboxylic acid are functional isomers of

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  5. Compound having molecular formula C(3)H(6)O(2) is:-

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  6. Which of the following formula represent chloroethanoic acid ?

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  7. Fatty acids are

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  8. General formula for mono-carboxylic acid is :

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  9. Which of the following is example of tricarboxylic acid ?

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  10. Glacial acetic acid is the same as :

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  11. Which of the follwong compound does not have a carboxyl group.

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  12. Acetic acid is a weak acid because :

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  13. Which one of the following is ethanoic acid ?

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  14. The common name of CH(3)(CH(2))(16)COOH acid is :

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  15. The I.U.P.A.C. name of CH(3)-CH(2)-underset(CH(3))underset(|)(C)H-CH(2...

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  16. The I.U.P.A.C. name of lactic acid CH(3)CHOHCOOH is :

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  17. The IUPAC name of the compound :

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  18. Which of the following acids occur in ants ?

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  19. Most of the carboxylic acids exists as dimer in

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  20. Acetic acid can be separated from aqeous solution of acetic acid,at wh...

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  21. Which of the following is isobutyric acid?

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