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Grignard reagent on reaction with hydrog...

Grignard reagent on reaction with hydrogen cyanide followed by hydrolysis will form

A

Aldehydes

B

Ketones

C

Esters

D

Acid Amides

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To solve the problem of what is formed when a Grignard reagent reacts with hydrogen cyanide followed by hydrolysis, we can break down the process into clear steps: ### Step-by-Step Solution: 1. **Understanding Grignard Reagents**: - Grignard reagents are organomagnesium compounds represented as RMgX, where R is an organic group (alkyl or aryl) and X is a halogen. The carbon atom in R carries a partial negative charge, making it a nucleophile. **Hint**: Remember that Grignard reagents act as nucleophiles due to the polar bond between carbon and magnesium. 2. **Reaction with Hydrogen Cyanide (HCN)**: - When a Grignard reagent (RMgX) reacts with hydrogen cyanide (HCN), the nucleophilic carbon (R) attacks the electrophilic carbon of the cyanide (C≡N). This results in the formation of an intermediate compound. **Hint**: Look for the nucleophilic attack of R on the carbon of the cyanide group. 3. **Formation of an Intermediate**: - The reaction can be represented as: \[ R-MgX + HCN \rightarrow R-CH(NH)C \text{ (intermediate)} \] - This intermediate has a carbon atom bonded to a nitrogen atom (which has a negative charge). **Hint**: The intermediate contains a carbon-nitrogen bond and will be unstable due to the negative charge on nitrogen. 4. **Hydrolysis of the Intermediate**: - Upon hydrolysis, the intermediate reacts with water. The nitrogen atom can abstract a proton from water, leading to the formation of an amine and a hydroxyl group. **Hint**: Hydrolysis involves the addition of water, which will facilitate the conversion of the intermediate into a more stable product. 5. **Final Product Formation**: - After hydrolysis, the final product will be an aldehyde (RCHO) and ammonia (NH3) as a byproduct. The reaction can be summarized as: \[ R-CH(NH2)C + H2O \rightarrow R-CHO + NH3 \] **Hint**: The final product is an aldehyde, which is characterized by the functional group -CHO. ### Conclusion: When a Grignard reagent reacts with hydrogen cyanide followed by hydrolysis, the final product formed is an aldehyde (RCHO). ### Final Answer: The product formed is an aldehyde (RCHO).

To solve the problem of what is formed when a Grignard reagent reacts with hydrogen cyanide followed by hydrolysis, we can break down the process into clear steps: ### Step-by-Step Solution: 1. **Understanding Grignard Reagents**: - Grignard reagents are organomagnesium compounds represented as RMgX, where R is an organic group (alkyl or aryl) and X is a halogen. The carbon atom in R carries a partial negative charge, making it a nucleophile. **Hint**: Remember that Grignard reagents act as nucleophiles due to the polar bond between carbon and magnesium. ...
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MARVEL PUBLICATION-ALDEHYDES,KETONES AND CARBOXYLIC ACIDS-CARBOXYLIC ACIDS
  1. Grignard reagent on reaction with hydrogen cyanide followed by hydroly...

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  2. In the case of carboxylic acids,the alpha-carbon is the carbon:

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  3. General formula for mono-carboxylic acid is :

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  4. Aliphatic carboxylic acid are functional isomers of

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  5. Compound having molecular formula C(3)H(6)O(2) is:-

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  6. Which of the following formula represent chloroethanoic acid ?

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  7. Fatty acids are

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  8. General formula for mono-carboxylic acid is :

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  9. Which of the following is example of tricarboxylic acid ?

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  10. Glacial acetic acid is the same as :

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  11. Which of the follwong compound does not have a carboxyl group.

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  12. Acetic acid is a weak acid because :

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  13. Which one of the following is ethanoic acid ?

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  14. The common name of CH(3)(CH(2))(16)COOH acid is :

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  15. The I.U.P.A.C. name of CH(3)-CH(2)-underset(CH(3))underset(|)(C)H-CH(2...

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  16. The I.U.P.A.C. name of lactic acid CH(3)CHOHCOOH is :

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  17. The IUPAC name of the compound :

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  18. Which of the following acids occur in ants ?

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  19. Most of the carboxylic acids exists as dimer in

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  20. Acetic acid can be separated from aqeous solution of acetic acid,at wh...

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  21. Which of the following is isobutyric acid?

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