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In the reaction , CH(3)CHO + HCN rarr ...

In the reaction ,
`CH_(3)CHO + HCN rarr A underset(H_(2)O)overset(H^(+))(rarr) B `
The product B is ?

A

`CH_(3)COH(CH_(3))CH(2)COCH_(3)`

B

`CH_(3)C(OH)(CH_(3))CH_(2)COOH`

C

`CH_(3)CH(OH)CO OH`

D

`CH_(3)CH=CHCH_(2)COCH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction step by step, let's analyze the reactants and products involved. ### Step 1: Identify the Reactants The reaction involves: - **Reactant 1**: Acetaldehyde (CH₃CHO) - **Reactant 2**: Hydrogen cyanide (HCN) ### Step 2: Nucleophilic Addition Reaction When acetaldehyde (CH₃CHO) reacts with hydrogen cyanide (HCN), the cyanide ion (CN⁻) acts as a nucleophile. It attacks the electrophilic carbon atom of the carbonyl group (C=O) in acetaldehyde. - The reaction can be represented as: \[ CH₃CHO + HCN \rightarrow CH₃C(OH)(CN) \] This intermediate product is known as a cyanohydrin (A). ### Step 3: Protonation of the Intermediate In the presence of an acid (H⁺) and water (H₂O), the cyanohydrin undergoes hydrolysis. The hydroxyl group (OH) is formed from the addition of water, and the cyanide group (CN) is converted into a carboxylic acid. - The reaction can be represented as: \[ CH₃C(OH)(CN) + H₂O \xrightarrow{H^+} CH₃C(OH)(COOH) + NH₃ \] Here, the CN group is converted to a carboxylic acid (COOH) and ammonia (NH₃) is released. ### Step 4: Final Product (B) The final product (B) is: \[ CH₃C(OH)(COOH) \] This compound is known as 2-hydroxybutanoic acid or lactic acid. ### Conclusion Thus, the product B formed after the hydrolysis of the intermediate cyanohydrin is a carboxylic acid with a hydroxyl group. ### Final Answer The product B is **2-hydroxybutanoic acid (lactic acid)**. ---

To solve the given reaction step by step, let's analyze the reactants and products involved. ### Step 1: Identify the Reactants The reaction involves: - **Reactant 1**: Acetaldehyde (CH₃CHO) - **Reactant 2**: Hydrogen cyanide (HCN) ### Step 2: Nucleophilic Addition Reaction ...
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MARVEL PUBLICATION-ALDEHYDES,KETONES AND CARBOXYLIC ACIDS-CARBOXYLIC ACIDS
  1. In the reaction , CH(3)CHO + HCN rarr A underset(H(2)O)overset(H^(+)...

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  2. In the case of carboxylic acids,the alpha-carbon is the carbon:

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  3. General formula for mono-carboxylic acid is :

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  4. Aliphatic carboxylic acid are functional isomers of

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  5. Compound having molecular formula C(3)H(6)O(2) is:-

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  6. Which of the following formula represent chloroethanoic acid ?

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  7. Fatty acids are

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  8. General formula for mono-carboxylic acid is :

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  9. Which of the following is example of tricarboxylic acid ?

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  10. Glacial acetic acid is the same as :

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  11. Which of the follwong compound does not have a carboxyl group.

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  12. Acetic acid is a weak acid because :

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  13. Which one of the following is ethanoic acid ?

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  14. The common name of CH(3)(CH(2))(16)COOH acid is :

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  15. The I.U.P.A.C. name of CH(3)-CH(2)-underset(CH(3))underset(|)(C)H-CH(2...

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  16. The I.U.P.A.C. name of lactic acid CH(3)CHOHCOOH is :

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  17. The IUPAC name of the compound :

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  18. Which of the following acids occur in ants ?

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  19. Most of the carboxylic acids exists as dimer in

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  20. Acetic acid can be separated from aqeous solution of acetic acid,at wh...

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  21. Which of the following is isobutyric acid?

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