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A compound (A) C(5)H(10) Cl(2) on hydrol...

A compound (A) `C_(5)H_(10) Cl_(2)` on hydrolysis gives `C_(5)H_(10)O` which reacts with `NH_(2)OH`, forms iodoform but does not give Fehling test (A) is :

A

`CH_(3)-underset(Cl)underset(|)overset(Cl)overset(|)(C)-CH_(2)-CH_(2)-CH_(3)`

B

`CH_(3)CH_(2)-underset(Cl)underset(|)overset(Cl)overset(|)(C)-CH_(2)CH_(3)`

C

`CH_(3)CH_(2)CH_(2)CH_(2)underset(Cl)underset(|)overset(Cl)overset(|)(C)H`

D

`CH_(3)-overset(Cl)overset(|)(C)H-overset(Cl)overset(|)(C)H-CH_(2)-CH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
A

As A reacts with hydroxylamine it means A may be aldehyde or ketone, but it does not react with Fehling solution hence A must be a ketone.Secondly it forms iodoform which is a characteristic reaction of methyl keton.
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MARVEL PUBLICATION-ALDEHYDES,KETONES AND CARBOXYLIC ACIDS-CARBOXYLIC ACIDS
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  8. General formula for mono-carboxylic acid is :

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