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The complex ion [Cu(NH(3))(4)]^(2+) is...

The complex ion `[Cu(NH_(3))_(4)]^(2+)` is

A

Tetrahedral

B

Square planar

C

Both

D

None of these.

Text Solution

Verified by Experts

The correct Answer is:
B
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The complex ion [Cu(NH_(3))_(4)]^(2+) has

In an excess of NH_(3(aq.)),Cu^(2+) ion form a deep blue complex ion [Cu(NH_(3))_(4)]^(2+) having formation constant K_(f)=5.6xx10^(11) . Calculate the concentration of Cu^(2+) in a solution prepared by adding 5.0xx10^(-3) mole of CuSO_(4) to 0.50 litre of 0.40M NH_(3) .

Assertion: Complex ion [Co(NH_(3))_(6)]^(2+) is readily oxidized to [Co(NH_(3))_(6)]^(3+) Reason: Unpaired electron in complex ion [Co(NH_(3))_(6)]^(2+) is present in 4p orbital.

IUPAC name of the complex [Cu(NH_(3))_(4)]SO_(4) is