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[Fe(NO(2))(3)Cl(3)] and [Fe(O-NO)(3)Cl(3...

`[Fe(NO_(2))_(3)Cl_(3)]` and `[Fe(O-NO)_(3)Cl_(3)]` show

A

Linkage isomerism

B

Geometrical isomerism

C

Optical isomerism

D

None of the above.

Text Solution

Verified by Experts

The correct Answer is:
A
`[Fe(NO_(2))_(3)Cl_(3)]` and `[Fe(ONO)_(3)Cl_(3)]` show linkage isomerism. This type of isomerism is shown by the complexes in which an ambidentate ligand is present.
`NO_(2)^(-),SCN^(-),CN^(-)` etc. are ambidentate ligand as each of them contain more than one donor sites. In the linkage isomerism, at a time only one donor atom of ligand is bonded to metal atom and hence arises linkage isomerism.
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NIKITA PUBLICATION-CO-ORDINATION COMPOUNDS -MCQs
  1. Which of the following complex will give a white precipitate on treatm...

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  2. Complexometric titrations involve use of

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  3. [Fe(NO(2))(3)Cl(3)] and [Fe(O-NO)(3)Cl(3)] show

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  4. The pair in which both species have same magnetic moment (spin only va...

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  5. Which of the following can participate in linkage isomerism ?

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  6. The hardness of water is measured by

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  7. When ammonia is added to AgCl, the following is /are correct observati...

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  8. Wht will be the theoretical value of magnetic moment (mu) when CN^(-) ...

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  9. Which of the following complex ions is expected to absorb visible ligh...

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  10. The reaction [Fe(CNS)6]^(3-)rarr[FeF6]^(3-) takes place with:

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  11. An example for a double salt is

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  12. Which of the following facts about the complex [Cr(NH(3))(6)]Cl(3) is...

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  13. K(4)[Fe(CN)(6)] is a

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  14. Some salts although containing two different metallic elements give te...

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  15. The EAN of iron in [Fe(CN)(6)]^(3-) is

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  16. Coordination number of Ni in [Ni(C2O4)3]^(4-) is:

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  17. According to Lewis, the ligands are

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  18. According to the postulates of Werner for cooedination compounds

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  19. In[Co(NH(3))(6)]Cl(3),the number of covalent bonds is

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  20. Chemical formula for iron (III) hexacyanoferrate (II) is

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