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Which of the following facts about the c...

Which of the following facts about the complex `[Cr(NH_(3))_(6)]Cl_(3)` is wrong ?

A

The complex involves `d^(2)sp^(3)` hybridisation and is octahedral in shape

B

The complex is paramagnetic

C

The complex is an outer orbital complex

D

The complex gives while precipitate with silver nitrate

Text Solution

Verified by Experts

The correct Answer is:
C

In case of `d^(3)` configuration, the number of unpaired electrons remains 3 whether the ligand is strong field or weak filed. The hybridisation scheme can be shown as follow `[Cr(NH_(3))_(3)]^(3+)`=

Hence the complex is inner orbital complex as it involves (n-1)d orbitals hybridisation, `3.93=sqrt(n(n+2))`, so n=3 (here n is number of unpaired electron (s)).
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