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MnO(4)^(2-) (1 mole) in neutral aqueous ...

`MnO_(4)^(2-)` (1 mole) in neutral aqueous medium disproportionates to

A

2/3 mole of `MnO_(4)^(-) and 1//3` mole of `MnO_(2)`

B

1/3 mole of `MnO_(4)^(-) and 2//3` mole of `MnO_(2)`

C

1/3 mole of `Mn_(2)O_(7) and 1//3 ` mole of `MnO_(2)`

D

2/3 mole of `Mn_(2)O_(7) and 1//3` mole of `MnO_(2)`

Text Solution

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The correct Answer is:
A

`3MnO_(4)^(2)+2H_(2)O to MnO_(2)+2MnO_(4)^(-)+4OH^(-)`
or `MnO_(4)^(2-)+(2)/(3)H_(2)O to (1)/(3)MnO_(2)+(2)/(3)MnO_(4)^(-)+(4)/(3)OH^(-)`
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