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Banzaldehyde can be prepared by oxidatio...

Banzaldehyde can be prepared by oxidation of toluene by

A

Acidic `KMnO_(4)`

B

`K_(2) Cr_(2) O_(7)`

C

`CrO_(2) Cl_(2)`

D

All of these

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The correct Answer is:
To prepare benzaldehyde from toluene through oxidation, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The starting material is toluene, which is also known as methylbenzene (C6H5CH3). 2. **Choose the Oxidizing Agent**: - To oxidize toluene to benzaldehyde, we need an appropriate oxidizing agent. In this case, chromium chloride (CrO2Cl2) is a suitable choice. 3. **Set Up the Reaction Conditions**: - The reaction typically takes place in a solvent, which in this case is carbon disulfide (CS2). 4. **Conduct the Reaction**: - When toluene (C6H5CH3) is treated with chromium chloride (CrO2Cl2) in the presence of carbon disulfide, it undergoes oxidation. 5. **Hydrolysis**: - After the oxidation step, the product is subjected to hydrolysis. This step converts the intermediate formed during oxidation into benzaldehyde (C6H5CHO). 6. **Final Product**: - The final product of this reaction is benzaldehyde, which is the desired aldehyde. ### Conclusion: The oxidation of toluene to benzaldehyde can be achieved using chromium chloride (CrO2Cl2) as the oxidizing agent, followed by hydrolysis. ### Answer: Benzaldehyde can be prepared by oxidation of toluene using chromium chloride (CrO2Cl2). ---
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  2. Aldehydes with alpha-H atom do not undergo disproportionation because:

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  4. In Cannizzaro reaction, which of the following is a better hydride don...

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  5. Mark the correct order of increasing reactivity.

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  6. Compound (A) given below can undergo Cannizzaro reaction itself and cr...

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  7. CH3 CH=CHCHO is oxidised to CH3 CH=CHCOOH using :

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  8. Clemmensen's reduction will convert cyclohexanone into:

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  9. What of the following is expected to be most highly ionised in water ?

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  10. Ethylidene chloride is hydrolysed with aqueous NaOH. The product forme...

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  11. The vapours of ethyl alcohol are passed over red hot copper at 573 K t...

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  13. The chemical reaction of acetaldehyde and ammonia results in:

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  14. When diethyl cadmium [(C(2)H(5))(2)Cd] is treated with acetyl chloride...

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  15. The product formed by the reaction of acetaldehyde with excess of etha...

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  17. In order to prepare acetone from acetyl chloride in one step, which of...

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  18. Which of the following reagents can help in separating a mixture of ac...

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  19. The reagents used to convert

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  20. Which of the following is the stronger acid?

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  21. Of the following which compound is an acetal ?

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