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The major product H of the given reactio...

The major product `H` of the given reaction sequence is
`CH_(3) - CH_(2) CO - CH_(3) overset (Theta_(CN)) to G - overset (95% H_(2) SO_(4)) underset (Heat) to H`

A

`CH_(3)-CH=underset(CH_(3))underset(|)(C)-COOH`

B

`CH_(3)-CH=underset(CH_(3))underset(|)(C)-CN`

C

`CH_(3)-CH_(2)-overset(OH)overset(|)underset(CH_(3))underset(|)(C)-COOH`

D

`CH_(3)-CH=underset(CH_(3))underset(|)(C)-CO-NH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the major product \( H \) of the given reaction sequence, we will follow these steps: ### Step 1: Identify the starting material The starting material is \( CH_3 - CH_2 - CO - CH_3 \), which can be represented as: \[ CH_3 - CH_2 - C(=O) - CH_3 \] This is butan-2-one. ### Step 2: Nucleophilic addition of cyanide The reaction involves the addition of a cyanide ion \( CN^- \) to the carbonyl group. In a nucleophilic addition reaction, the cyanide ion attacks the carbon atom of the carbonyl group, leading to the formation of a cyanohydrin. The reaction can be illustrated as follows: 1. The \( CN^- \) attacks the carbonyl carbon. 2. The double bond between carbon and oxygen shifts to the oxygen, forming an alkoxide ion. The intermediate product \( G \) can be represented as: \[ CH_3 - CH_2 - C(CN)(OH) - CH_3 \] ### Step 3: Acidic hydrolysis Next, we treat the intermediate \( G \) with 95% \( H_2SO_4 \) and heat it. The acidic conditions will lead to hydrolysis of the cyanide group: 1. The \( CN \) group will be converted to a carboxylic acid \( COOH \) and ammonia \( NH_3 \). 2. The alkoxide ion \( O^- \) will be protonated to form \( OH \). The resulting compound after hydrolysis will be: \[ CH_3 - CH_2 - C(OH) - CH_3 \] ### Step 4: Elimination to form an alkene Upon heating, we will undergo a dehydration reaction where water is eliminated. The hydroxyl group \( OH \) and a hydrogen atom from an adjacent carbon will be removed, leading to the formation of an alkene. The possible elimination can yield two products: 1. \( CH_3 - CH = C - CH_3 \) (but-2-ene) 2. \( CH_3 - C = CH - CH_3 \) (but-1-ene) However, the more stable product will be the one with the greater number of alkyl substituents on the double bond due to hyperconjugation. ### Step 5: Determine the major product The major product \( H \) will be: \[ CH_3 - C = CH - CH_3 \] This is but-2-ene, which is more stable due to hyperconjugation. ### Final Answer Thus, the major product \( H \) of the reaction sequence is: \[ CH_3 - C = CH - CH_3 \]

To determine the major product \( H \) of the given reaction sequence, we will follow these steps: ### Step 1: Identify the starting material The starting material is \( CH_3 - CH_2 - CO - CH_3 \), which can be represented as: \[ CH_3 - CH_2 - C(=O) - CH_3 \] This is butan-2-one. ### Step 2: Nucleophilic addition of cyanide ...
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A2Z-ALDEHYDES, KETONES AND CARBOXYLIC ACID-Section D - Chapter End Test
  1. The major product H of the given reaction sequence is CH(3) - CH(2) ...

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  2. Aldehydes with alpha-H atom do not undergo disproportionation because:

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  3. Which of the following tests would help in the distinction of HCOOH an...

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  4. In Cannizzaro reaction, which of the following is a better hydride don...

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  5. Mark the correct order of increasing reactivity.

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  6. Compound (A) given below can undergo Cannizzaro reaction itself and cr...

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  7. CH3 CH=CHCHO is oxidised to CH3 CH=CHCOOH using :

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  8. Clemmensen's reduction will convert cyclohexanone into:

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  9. What of the following is expected to be most highly ionised in water ?

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  10. Ethylidene chloride is hydrolysed with aqueous NaOH. The product forme...

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  11. The vapours of ethyl alcohol are passed over red hot copper at 573 K t...

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  12. (CH(3))(2) CHOH overset ("Mild") underset ("oxidation"[0]) to (X) over...

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  13. The chemical reaction of acetaldehyde and ammonia results in:

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  14. When diethyl cadmium [(C(2)H(5))(2)Cd] is treated with acetyl chloride...

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  15. The product formed by the reaction of acetaldehyde with excess of etha...

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  16. Which of the following will not be formed when calcium formate is dist...

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  17. In order to prepare acetone from acetyl chloride in one step, which of...

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  18. Which of the following reagents can help in separating a mixture of ac...

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  19. The reagents used to convert

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  20. Which of the following is the stronger acid?

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  21. Of the following which compound is an acetal ?

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