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Strongest acid among the following is...

Strongest acid among the following is

A

`CH_(3)COOH`

B

`FCH_(2)COOH`

C

`F_(2)CHCOOH`

D

`F_(3)C-COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the strongest acid among the given options, we need to analyze the structure of each carboxylic acid and the presence of electron-withdrawing groups that can stabilize the conjugate base formed after deprotonation. ### Step-by-Step Solution: 1. **Identify the Structure of Each Acid:** - Option A: CH3C(=O)OH (Acetic Acid) - Option B: FCH2C(=O)OH (Fluoroacetic Acid) - Option C: F2CHC(=O)OH (Difluoroacetic Acid) - Option D: F3C(=O)OH (Trifluoroacetic Acid) 2. **Understand the Concept of Acidity:** - The acidity of a carboxylic acid is influenced by the stability of its conjugate base (the carboxylate ion formed after losing a proton). - A more stable conjugate base corresponds to a stronger acid. 3. **Analyze the Electron-Withdrawing Groups:** - Electron-withdrawing groups (EWGs) stabilize the negative charge on the conjugate base, making the acid stronger. - The strength of the EWG effect increases with the number of electronegative atoms attached to the carbon adjacent to the carboxylic group. 4. **Evaluate Each Option:** - **Option A (Acetic Acid)**: Contains a methyl group (CH3) which has a +I effect (electron-donating), making it a weaker acid. - **Option B (Fluoroacetic Acid)**: Contains one fluorine atom, which has a -I effect, providing some stabilization to the conjugate base. - **Option C (Difluoroacetic Acid)**: Contains two fluorine atoms, which increases the -I effect, making the conjugate base more stable than that of Fluoroacetic Acid. - **Option D (Trifluoroacetic Acid)**: Contains three fluorine atoms, providing the strongest -I effect, leading to maximum stabilization of the conjugate base. 5. **Conclusion:** - Based on the analysis, Trifluoroacetic Acid (Option D) has the strongest electron-withdrawing effect due to the presence of three fluorine atoms. This results in the greatest stabilization of its conjugate base, making it the strongest acid among the options provided. ### Final Answer: The strongest acid among the given options is **Option D: Trifluoroacetic Acid (F3C(=O)OH)**.

To determine the strongest acid among the given options, we need to analyze the structure of each carboxylic acid and the presence of electron-withdrawing groups that can stabilize the conjugate base formed after deprotonation. ### Step-by-Step Solution: 1. **Identify the Structure of Each Acid:** - Option A: CH3C(=O)OH (Acetic Acid) - Option B: FCH2C(=O)OH (Fluoroacetic Acid) - Option C: F2CHC(=O)OH (Difluoroacetic Acid) ...
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