Home
Class 12
CHEMISTRY
CH(3) CO(2) C(2) H(5) on reaction with s...

`CH_(3) CO_(2) C_(2) H_(5)` on reaction with sodium ethoxide in ethanol gives `A`, which on heating in the presence of acid gives `B` compound `B` is

A

`CH_(3)COCH_(2)COOH`

B

`CH_(2)COCH_(3)`

C

D

Text Solution

Verified by Experts

The correct Answer is:
B

`CH_(3)COOC_(2)H_(5)+CH_(5)-overset(O)overset(||)(C)-OC_(2)H_(5)overset(C_(2)H_(5)ONa)to`
`CH_(3)-overset(O)overset(||)(C)-CH_(2)-COOC_(2)H_(5)overset(H^(+))to`
`CH_(3)-COCH_(2)COOHoverset("Heat")toCH_(3)-overset(O)overset(||)(C)-CH_(3)+CO_(2)`
`beta`-Keto acids, on heating undergo decarboxylation
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES, KETONES AND CARBOXYLIC ACID

    A2Z|Exercise Assertion-Reasoning Questions|7 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACID

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACID

    A2Z|Exercise AIPMT/NEET Questions|43 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • BIOMOLECULES

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

Cyclopentane on heating with bromine gives compound (A) which on reaction with sodium ethoxide in ethanol, gives (B), Compound (B) on reaction with NBS in presence of peroxide gives (C) .Identify (A), (B) and (C) .

on reaction with CH_(3)OH in presence of H^(+) gives :

Compound (A) C_(5)H_(8)O_(2) liberated CO_(2) on reaction with sodium bicarbonate. It exists in two forms neither of which is optically active. It yielded compound (B) C_(5)H_(10)O_(2) on hydrogenation. Compound (B) can be separated into enantiomorphs. Write structures of (A) and (B).

An organic compound (A) (C_(6)H_(10)O) on reaction with CH_(3)MgBr followed by acid treatment gives compound (B). The compound (B) on ozonolysis gives compound (C ), which in the presence of a base gives 1-acetyl cyclopentane (D). The compound (B) on reaction with HBr gives compound (E ). Write the structures of (A), (B), (C ), (D), and (E ). Show how (D) is formed from (C ).

A2Z-ALDEHYDES, KETONES AND CARBOXYLIC ACID-AIIMS Questions
  1. The regent used for the sepration of acetaldehyde from acetophenone is

    Text Solution

    |

  2. o-Toluic acid on reaction with Br(2) + Fe gives

    Text Solution

    |

  3. CH(3) CO(2) C(2) H(5) on reaction with sodium ethoxide in ethanol give...

    Text Solution

    |

  4. The following sequence of reaction on Agives

    Text Solution

    |

  5. Isopropylbenzne on air oxidation in the presence of dilute acid gives

    Text Solution

    |

  6. The product obtained is//are

    Text Solution

    |

  7. Benzoic acid is treat with lithum aluminium hydride.

    Text Solution

    |

  8. CH(3)CH(2)C = N overset (X) to CH(3)CH(2)OH The compound X is

    Text Solution

    |

  9. Which of these compound is synthesised by chloral?

    Text Solution

    |

  10. Prologed exposure of far or oil in moist air and light causes had smel...

    Text Solution

    |

  11. 3-hydroxybutanal formed when X reacts whith Y in dilute Z solution. Wh...

    Text Solution

    |

  12. In the reaction Mg-Br is the treated with CH(3)CN and then hydrolys...

    Text Solution

    |

  13. In the following soquency of the reaction , identify the final product

    Text Solution

    |

  14. In a Cannizaro reaction the intermediate that will be the best hydride...

    Text Solution

    |

  15. Compound A (molecular formula C(3)H(8)O)is treated with acidified pota...

    Text Solution

    |

  16. Ethyl ester overset(MeMgBr) underset(excess)rarr P. The product P will...

    Text Solution

    |

  17. (CH(3))(3) C - CHO does not undergo aldol condensation due to

    Text Solution

    |

  18. Maximum decarboxylation accurs in

    Text Solution

    |

  19. Which of the following undergoes haloform reaction? (i) CH(3)CH(2)CO...

    Text Solution

    |

  20. If phthalic acid is treated with NH(3) and then it is first heated wea...

    Text Solution

    |