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3-hydroxybutanal formed when X reacts wh...

3-hydroxybutanal formed when X reacts whith Y in dilute Z solution. What are X, Y, and Z?

A

`X = CH_(3)CHO, Y = (CH_(3))_(2)CO, Z = NaOH`

B

`X = CH_(3)CHO, Y = CH_(3)CHO, Z = NaCI`

C

`X = (CH_(3))_(2)CO, Y = (CH_(3))_(2)CO, Z = HCI`

D

`X = CH_(3)CHO, Y = CH_(3)CHO, Z = NaOH`

Text Solution

Verified by Experts

The correct Answer is:
D

The product obtained is
`CH_(3)-underset(OH)underset(|)(CHCH_(2)CHO`
This product is obtained when `2`molecules of `CH_(3)CHO` are heated with concentrated alkali `(NaOH)`
`CH_(3)underset(X)(CHO)+underset(Y)(CH_(3))CHOoverset(NaOH)underset(Z)to`
`CH_(3)underset(OH)underset(|)CH-CH_(2)-CHO`
The aldehydes having `alpha`-hydrogen atom on heating with concentrated alkali give brown mass, aldol condensation.
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