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A compound with formula C5H(13) gives a ...

A compound with formula `C_5H_(13)` gives a base soluble derivative iin the Hinsberg test `(C_6H_5SO_2Cl` in base). Which of the following best satisfy this condition?

A

2,2-dimethylpropylamine

B

Isopropyldimethylamine

C

N,N-dimethylpropylamine

D

N-methyl-2-methylpropylamine

Text Solution

Verified by Experts

The correct Answer is:
A
`CH_(3)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)(C)-CH_(2)-NH_(2)+CHCl_(3)+3KOH`
`rarr(CH_(3))_(3)C CH_(2)NC+3KCl+3H_(2)O`
This is the property of `1^@` amine (i.e., compound having-`NH_2`) group. Thus 2,2- dimethylpropylamine gives this reaction.
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A2Z-ORGANIC COMPOUNDS CONTAINING NITROGEN-Section D - Chapter End Test
  1. A compound with formula C5H(13) gives a base soluble derivative iin th...

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  2. Which of the following nitro compounds will show tautomerism?

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  3. Gabriel synthesis is used for the preparation of

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  4. The major product of the reaction is:

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  5. Which of the following statement is correct?

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  6. Which of the following is the weakest base?

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  7. Only one the following amines will lose its nitrogen atom as trimehyl ...

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  8. Which of the following cannot react with HNO2?

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  9. In order to distinguigh between C2H5NH2 and C6H5NH2 which of the fol...

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  10. Which of the following amines reacts most rapidly with

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  11. Which of the following produces one mononitro and three isomeric dinit...

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  12. The conjugate base of (CH3)2NH2^(Theta) is:

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  13. Identify major product of following sequency of reaction:

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  14. Primary and secondary amines are distinguished by:

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  15. The product of the reaction of alcoholic silver nitrite with ethyl bro...

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  16. Identify the final product of following sequence of reaction:

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  17. Tertiary nitro compounds cannot show tautomerism becauses :

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  18. When C6H5N2Cl is reduced with Na2SnO2, the product is:

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  19. Identify final product of following sequence of reaction:

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  20. Which of the following substances on treatment with P2O5 gives ethanen...

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  21. Which of the following reagents on treatment with benzenamine in basic...

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