Home
Class 12
CHEMISTRY
p-chloro aniline and anilinium hydrochlo...

p-chloro aniline and anilinium hydrochloride can be distinguished by

A

Sandmeyer's reaction

B

`AgNO_3`

C

Liebermann's nitroso reaction

D

Carbylamine test

Text Solution

Verified by Experts

The correct Answer is:
B

`AgNO_3` gives white ppt. of `AgCl` with anilinium hydrochloride because of the presence of free chlorine in it but p-chloroaniline gives no reaction with it. Hence, `AgNO_3` can be used to distinguish them.
Promotional Banner

Topper's Solved these Questions

  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    A2Z|Exercise Nitrocyanide And Isocyanides|32 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    A2Z|Exercise Section B - Assertion Reasoning|11 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • ORGANIC COMPOUNDS CONTAINING HALOGENS

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • P BLOCK ELEMENTS ( GROUP 15,16,17,18)

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

p-chloroaniline and anilinium hydrochloride cannot be distinguished by

p- chloroaniline and anilinium hydrogen chloride can be distinguished by

Male Ascaris can be distinguished by

A2Z-ORGANIC COMPOUNDS CONTAINING NITROGEN-Aromatic Amines And Diazonium Salts
  1. Oil of mirbane is

    Text Solution

    |

  2. A student tried to synthesis 4-nitro-N, N-dimethylaniline from N, N-di...

    Text Solution

    |

  3. p-chloro aniline and anilinium hydrochloride can be distinguished by

    Text Solution

    |

  4. By reduction of mitrosobenzene which f the following is not obtained

    Text Solution

    |

  5. Among the following compounds nitrobenzene, benzene, aniline and pheno...

    Text Solution

    |

  6. An organic compound A has molecular formula C7H9N and it forms a clear...

    Text Solution

    |

  7. Aniline on treatment with excess of bromine water gives

    Text Solution

    |

  8. Which could not be directly prepared from 4-bromobenzenediazonium ion?

    Text Solution

    |

  9. When an organic compound was treated with sodium nitrite and hydrochlo...

    Text Solution

    |

  10. Derice a series of reaction of convert benzene into metachlorobromoben...

    Text Solution

    |

  11. Aniline reacts with alkyl halide to give

    Text Solution

    |

  12. Which of the following is regenerated at the end of the reaction?

    Text Solution

    |

  13. Which of the following compounds does not react with NaNO2 and HCl?

    Text Solution

    |

  14. An azo compoudn X is cleaved at the azo linkage by stannous chloride S...

    Text Solution

    |

  15. Which one is less alkaline?

    Text Solution

    |

  16. In the diazotasation of aniline with sodium nitrite and hydrochloric a...

    Text Solution

    |

  17. Aniline and methyl amine can be differentiated by

    Text Solution

    |

  18. Reaction of aniline with benzaldehyde is

    Text Solution

    |

  19. In the reaction C6H5CHO+C6H5NH2rarrC6H5N=HCC6H5+H2O and compound C6H5N...

    Text Solution

    |

  20. Electrophilic substitution of with bromine gives

    Text Solution

    |