Home
Class 12
CHEMISTRY
Nitration of aniline also gives m-nitro ...

Nitration of aniline also gives m-nitro anilime, in stron acidic medium because,

A

In electrophilic substitution reaction amino group is metal directive.

B

In spite of substitiuents nitro group always goes to m-position

C

In strong scidic medium, nitration of aniline is a nucleophilic substitution reaction

D

In strong acidic medium aniline present as anilinium ion

Text Solution

Verified by Experts

The correct Answer is:
D


The reason for this is that , in acidic condition protonation of `-NH_2` group gives anilinium ion `(+NH_3)`, which is of deactivating nature and of m-directive nature.
Promotional Banner

Topper's Solved these Questions

  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    A2Z|Exercise Nitrocyanide And Isocyanides|32 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    A2Z|Exercise Section B - Assertion Reasoning|11 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • ORGANIC COMPOUNDS CONTAINING HALOGENS

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • P BLOCK ELEMENTS ( GROUP 15,16,17,18)

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

Nitration of aniline also gives m - nitroaniline along with o - nitro and p - nitroaniline , in strong acidic medium because

Nitration of benzonic acid gives

Nitration of aniline in strong acidic medium also gives m-nitroaniline because

Nitration of aniline in strong acidic medium also gives m-nitroaniline because

Nitration of benzoic acid gives m-nitrobenzoic acid.

A2Z-ORGANIC COMPOUNDS CONTAINING NITROGEN-Aromatic Amines And Diazonium Salts
  1. Benzldehyde condenses with N, N-dimethylaniline in presence of anhydro...

    Text Solution

    |

  2. The final product C, obtained in this reaction

    Text Solution

    |

  3. In the chemical reactions the compounds (A) and (B) are .

    Text Solution

    |

  4. Boverset(H(2))underset(Ni)(rarr)Coverset(HNO(2))(rarr)D Aniline in ...

    Text Solution

    |

  5. In the chemical reaction, compounds A and B respectively are

    Text Solution

    |

  6. Azo dye is prepared by the coupling of phenol and:

    Text Solution

    |

  7. Among the following the strongest base is

    Text Solution

    |

  8. Amongst the compounds gives, the one that would form a brilliant color...

    Text Solution

    |

  9. C6H5NH2overset(NaNO2HCl)toXoverset(Cu2(CN)2)toYoverset((X2)/(H^(+)))to...

    Text Solution

    |

  10. Nitration of aniline also gives m-nitro anilime, in stron acidic mediu...

    Text Solution

    |

  11. Examine the following two structures for the anilinium ion and choose ...

    Text Solution

    |

  12. Which of the following is the strongest base:

    Text Solution

    |

  13. A positive carbylmine test is given by

    Text Solution

    |

  14. The colours of p-amino azobenzene is

    Text Solution

    |

  15. Aniline when diazotized in cold and then treated with dimethyl aniline...

    Text Solution

    |

  16. Text Solution

    |

  17. In the following reaction, the structure of the major product (X) is:

    Text Solution

    |

  18. Aniline reacts with acetaldehyde to form

    Text Solution

    |

  19. (A) overset(NaNO(2)//HCl)underset((ii)H(2)//Ni)underset(0-5^(@))(rarr)...

    Text Solution

    |

  20. In the reaction, the structure of the product T is:

    Text Solution

    |