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Aniline reacts with acetaldehyde to form...

Aniline reacts with acetaldehyde to form

A

Schiff's base

B

Carbylamine

C

Immine

D

None of these

Text Solution

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The correct Answer is:
To determine the product formed when aniline reacts with acetaldehyde, we can follow these steps: ### Step 1: Identify the Reactants - Aniline is a primary amine with the structure C6H5NH2. - Acetaldehyde is a carbonyl compound with the structure CH3CHO. ### Step 2: Understand the Reaction Mechanism - When a primary amine (like aniline) reacts with an aldehyde (like acetaldehyde), they typically undergo a condensation reaction to form an imine (also known as a Schiff base). - The reaction involves the nucleophilic attack of the amine on the carbonyl carbon of the aldehyde. ### Step 3: Form the Intermediate - The nitrogen atom in aniline attacks the carbonyl carbon of acetaldehyde, leading to the formation of a tetrahedral intermediate. ### Step 4: Dehydration - The tetrahedral intermediate then undergoes dehydration (loss of water) to form the imine. - The general structure of the imine formed from aniline and acetaldehyde is C6H5N=CH(CH3). ### Step 5: Write the Final Product - The final product of the reaction is an imine, specifically N-ethylideneaniline, which can be represented as: \[ C6H5N=CH(CH3) \] ### Conclusion Thus, when aniline reacts with acetaldehyde, the product formed is an imine (Schiff base). ---

To determine the product formed when aniline reacts with acetaldehyde, we can follow these steps: ### Step 1: Identify the Reactants - Aniline is a primary amine with the structure C6H5NH2. - Acetaldehyde is a carbonyl compound with the structure CH3CHO. ### Step 2: Understand the Reaction Mechanism - When a primary amine (like aniline) reacts with an aldehyde (like acetaldehyde), they typically undergo a condensation reaction to form an imine (also known as a Schiff base). ...
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Knowledge Check

  • Aniline reacts with acetic anhydride to give

    A
    B
    C
    D
  • Aniline reacts with acetyl chloride to give

    A
    phenol
    B
    acetamide
    C
    acetanilide
    D
    benzene.
  • Which of the following will react with acetaldehyde to give white crystalline solide-soluble in water ?

    A
    `NaHSO_(4)`
    B
    `Na_(2)SO_(3)`
    C
    `NaHSO_(3)`
    D
    `Na_(2)CO_(3)`
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