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Diethyl oxalate is used for distinguishi...

Diethyl oxalate is used for distinguishing primary, secondary and tertiary

A

Alcohols

B

amines

C

alkyl halides

D

hydrogens in hydrocarbons

Text Solution

Verified by Experts

The correct Answer is:
B

Diethyl oxalate is used for distinguishing `1^@`,`2^@` and `3^@` amines as these amines react differently as dicussed below:
(i) The `1^@` amine forms corresponding substituted oxamide which is a crystalline solid:
(ii) While `2^@` amnine forms a diethyl oxamic ester which is a liquid
(iii) `3^@` amine does not react with diehtyl oxalatye since it does not contain a replacable hydrogen atom.
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