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The basic character of ethyl amine,dieth...

The basic character of ethyl amine,diethyl amine and triethyl amine in chlorobenzene is

A

`C_2H_5NH_2lt(C_2H_5)_2NHlt(C_2H_5)_3N`

B

`C_2H_5NH_2lt(C_2H_5)_3Nlt(C_2H_5)_2N`

C

`(C_2H_5)Nlt(C_2H_6)_2NHltC_2H_5NH_2`

D

`(C_2H_5)_3NltC_2H_5NH_2lt(C_2H_5)_2NH`

Text Solution

Verified by Experts

The correct Answer is:
A
In presence of chlorobanzene, hydrogen bonding is not possible between the protonated amine and the solvent and thus the stabilization factor (salvation effect) is absent. Hence basicity is explained on the basis of the number of electron releasing groups in an amine.
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Knowledge Check

  • Ethyl amine and dimethyl amine are

    A
    metamers
    B
    position isomer
    C
    chain isomers
    D
    function isomers

  • The basic character of amines is due to

    A
    presence of nitrogen atom
    B
    lone pair of electrons on nitrogen atom
    C
    tetrahedral structure
    D
    high electronegativity of nitrogen

  • The basic character of amines is because

    A
    They produce `OH^(-)` ions when treated with water
    B
    They have replaced H atoms on H atom
    C
    They have lone pair of electron on N atom
    D
    None of the reason is correct.

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