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A molecule is stable when the number of ...

A molecule is stable when the number of bonding orbitals is ________.

A

greater than the number of antibonding orbitals

B

greater than or equal to the number of antibonding orbitals

C

equal to the number of antibonding orbitals

D

less than the number of antibonding orbitals

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The distribution of electrons among molecular orbitals is called the electronic configuration of the molecule which provides us the following very important informations about the molecule. (A)Stability of molecule : The molecule is stable if number of bonding moleculer orbital electrons (N_b) is greater than the number of antibonding molecular orbital electrons (N_a) . (B) Bond order : Bond order =1/2(N_b-N_a) A positive bond order means a stable molecule while a negative or zero bond order means an unstable molecule. ( C)Nature of the bond : Bond order 1,2 and 3 corresponds to single , double and triple bonds respectively. (D)Bond length: Bond length decreases as bond order increases. (E)Magnetic nature: Molecular orbitals in a molecule are doubly occupied , the substance is diamagnetic and if one or more molecular orbitals are singly occupied, it is paramagnetic. N_2 has greater dissociation energy than N_2^+ , where as O_2 has a lower dissociation energy than O_2^+ because

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Atomic orbitals of bonded atoms combine to form molecular orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals taking part in the bond formation. When two atomic orbitals combine, two molecular orbitals are formed one of which has lower energy than the combining orbitals and is called bonding Molecular Orbital (MO). Whereas the other having higher energy than the two combining atomic orbitals is called Anti Bonding Molecular orbitals (ABMO) The two combining atomic orbitals must have comparable energies and should be properly oriented to allow considerable overlapping. If the overlapping is end to end along internuclear axis, the molecular orbital is called sigma and if the overlapping is lateral 1.e., sidewise the molecular orbital is called pie. Just like atomic orbitals, the molecular orbitals also have varying energy levels. Filling of electrons in molecular orbitals takes place following the same rules as followed for filing of atomic orbitals. The order of filling may not be same for all the molecules or their ions. Bond order is a useful parameter for comparing the various characteristics of molecules. The bond order (BO) in B_2 molecule is

TARGET PUBLICATION-NATURE OF CHEMICAL BOND-Evaluation test
  1. In a homologous series, the percentage of 's' character .

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  2. Which of the following molecule has two p-orbitals unused?

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  3. Energy required to dissociate 4g of gaseous hydrogen into free gaseous...

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  4. What happens when aluminium reacts with NaOH in presence of water mole...

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  5. What is the geometrical shape of [Pt(Cl)(4)]^(2-)?

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  6. Stability of the species Li(2), Li(2)^(-) and Li(2)^(+) increases in t...

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  7. Which of the following is NOT used to represent bond angles ?

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  8. The number of sigma bonds in CH(2)=CH - CH = CH - C -= CH is .

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  9. The stability of ionic crystal depends principally on

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  10. An example for an electron deficient molecule is .

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  11. Octahedral molecular shape exists in hybridisation.

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  12. The species having bond angles of 109^(@)28 is .

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  13. The bond angle in ammonia is 107^(@)18 due to .

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  14. A molecule is stable when the number of bonding orbitals is .

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  15. Which of the following molecules CANNOT exist under normal conditions?

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  16. The electronegativity values of C,H,O,N and S are 2.5, 2.1, 3.5, 3.0 a...

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  17. Find the CORRECT set with respect to molecule, hybridisation and shape...

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  18. If in a polar molecule, the ionic charge is 2.6 xx 10^(-10) e.s.u. and...

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  19. Which of the following does NOT show hydrogen bonding?

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  20. Which of the following theory provides good explanation about the para...

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