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A conductivity cell having cell constant...

A conductivity cell having cell constant `8.76 cm^(-1)` is placed in 0.01 M solution of an electrolyte offered a resistance of 1000 `"ohm"` . What is the condictivity of electrolytic solution ?

A

`8.76 xx 10^(4) "ohm"^(-1) cm^(-1)`

B

`8.76 xx 10^(-4) "ohm "^(-1) cm^(-1)`

C

`8.76 xx 10^(-3) "ohm"^(-1) cm^(-1)`

D

`8.76 xx 10^(-2) "ohm"^(-1) cm^(-1)`

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The correct Answer is:
To find the conductivity of the electrolytic solution, we will follow these steps: ### Step-by-Step Solution: 1. **Identify Given Values**: - Cell constant (k) = 8.76 cm⁻¹ - Resistance (R) = 1000 ohms 2. **Understand the Relationship**: The relationship between resistance (R), conductance (G), and conductivity (κ) is given by: \[ G = \frac{1}{R} \] and \[ G = k \cdot \kappa \] where: - G is the conductance, - k is the cell constant, - κ is the conductivity. 3. **Calculate Conductance (G)**: Using the resistance value: \[ G = \frac{1}{R} = \frac{1}{1000 \, \text{ohms}} = 0.001 \, \text{S} = 1 \times 10^{-3} \, \text{S} \] 4. **Relate Conductance to Conductivity**: From the relationship \( G = k \cdot \kappa \), we can express conductivity (κ) as: \[ \kappa = \frac{G}{k} \] 5. **Substitute Values**: Now, substituting the values of G and k: \[ \kappa = \frac{1 \times 10^{-3} \, \text{S}}{8.76 \, \text{cm}^{-1}} \] 6. **Calculate Conductivity**: Performing the calculation: \[ \kappa = \frac{1 \times 10^{-3}}{8.76} \approx 0.000112 \, \text{S/cm} = 8.76 \times 10^{-4} \, \text{S/cm} \] 7. **Final Result**: Therefore, the conductivity of the electrolytic solution is: \[ \kappa \approx 8.76 \times 10^{-3} \, \text{ohm}^{-1} \text{cm}^{-1} \]
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