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Fridel-crafts' reaction of bromobenzene ...

Fridel-crafts' reaction of bromobenzene with methyl iodide gives

A

o-bromotoluene

B

p-bromotoluene

C

o- and p-bromotoluenes

D

m-bromotoluene

Text Solution

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The correct Answer is:
C
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In both alkyl halides, The halogen atom is attached directly to the carbon atoms. They are expected to exhibit similar reactivity. However,aryl halides are comparatively little reactive, particularly towards nucleophilic substitution reactions. For example, hydrolysis of ethyl chloride takes place by simple boiling with aqueous KOH. On the other hand, the alkaline hydrolysis of chlorobenzene needs a very high temperature (623 K) as well as very high pressure Fridel craft reaction of bromo benzene with methyl iodide gives

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TARGET PUBLICATION-HALOGEN DERIVATIVES OF ALKANES AND ARENES-CRITICAL THINKING
  1. Which among the following structure represents sym-trichlorobenzene?

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  2. Chlorobenzene is .

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  3. Arrange the following compounds in order of increasing dipole moment: ...

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  4. Which of the following cannot be prepared by direct halogenations of b...

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  5. Benzenediazonium salt when simply mixed with KI, gives off .

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  6. The phenomenon in which atoms or groups in a compound can attract elec...

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  7. Example of species showing -I effect is .

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  8. It is easy to substitute -Cl in 2,4-dinitrochlorobenzene than in chlor...

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  9. In aryl halides , the reactivity is controlled by stronger and 0. p or...

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  10. Fridel-crafts' reaction of bromobenzene with methyl iodide gives

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  11. The commercial uses of DDT and benzene hexachloride are .

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  12. Which of the following statement about DDT is FASLE ?

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  13. Halogenation of alkanes is

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  14. RC-=N can be converted to RCH(2)NH(2) by .

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  15. For the reaction, C(2)H(5)OH + HX overset(ZnCl(2))to C(2)H(5)X+ H(2)O,...

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  16. The electron deficient reagents, which attack the negatively charged ...

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  17. Which of the following reactions does NOT show nucleophilic substituti...

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  18. Heterolytic fission gives rise to .

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  19. Heterolysis of carbon-chlorine bond produces .

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  20. In alkaline hydrolysis of tert-Butyl bromide, .

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