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Identify X and Y in the following sequen...

Identify X and Y in the following sequence
`C_(2)H_(5)Br overset(X) to "product" overset(Y) to C_(3)H_(7)NH_(2)`

A

X=KCn , `Y=LiAlH_(4)`

B

X=KCn, `Y=H_(3)O^(+)`

C

`X=CH_(3)Cl , Y=AlCl_(3)/HCl`

D

`X=CH_(3)NH_(2) , Y=HNO_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the reagents X and Y in the reaction sequence starting from ethyl bromide (C₂H₅Br) and ending with propylamine (C₃H₇NH₂). ### Step-by-Step Solution: 1. **Identify the starting material and the final product**: - Starting material: Ethyl bromide (C₂H₅Br) - Final product: Propylamine (C₃H₇NH₂) 2. **Determine the change in carbon atoms**: - Ethyl bromide has 2 carbon atoms. - Propylamine has 3 carbon atoms. - This indicates that one carbon atom is being added in the reaction. 3. **Identify the reagent X that adds one carbon atom**: - To add a carbon atom to a molecule, we can use a cyanide ion (CN⁻) which can be introduced through potassium cyanide (KCN). - The reaction of C₂H₅Br with KCN will yield ethyl cyanide (C₂H₅CN). 4. **Write the reaction for X**: - C₂H₅Br + KCN → C₂H₅CN (ethyl cyanide) 5. **Identify the product after the first reaction**: - The product after the reaction with KCN is ethyl cyanide (C₂H₅CN). 6. **Determine the reagent Y that converts ethyl cyanide to propylamine**: - Ethyl cyanide (C₂H₅CN) can be reduced to propylamine (C₃H₇NH₂) using a reducing agent. - A common reducing agent for this conversion is lithium aluminum hydride (LiAlH₄). 7. **Write the reaction for Y**: - C₂H₅CN + LiAlH₄ → C₃H₇NH₂ (propylamine) 8. **Final identification of X and Y**: - X = KCN (potassium cyanide) - Y = LiAlH₄ (lithium aluminum hydride) ### Conclusion: - The reagents are: - X = KCN - Y = LiAlH₄
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