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Number of molecules in lO0 cc of a gas a...

Number of molecules in lO0 cc of a gas at I 47. N.T.P. is ___ . if mass of each molecule is `4.556xx10^(-25)`kg and R.M.S speed is 350m/s.

A

`5.4xx10^(19)`

B

`5.4xx10^(21)`

C

`5.4xx10^(18)`

D

`5.4xx10^(23)`

Text Solution

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The correct Answer is:
To find the number of molecules in 100 cc of a gas at NTP, we can use the kinetic theory of gases and the relationship between pressure, density, and RMS speed. Here’s a step-by-step solution: ### Step 1: Understand the Given Data - Volume (V) = 100 cc = 100 x 10^(-6) m³ = 10^(-4) m³ - Mass of each molecule (m) = 4.556 x 10^(-25) kg - RMS speed (v_rms) = 350 m/s - Pressure at NTP (P) = 10^5 Pa ### Step 2: Use the Formula for Pressure According to the kinetic theory of gases, the pressure (P) can be expressed as: \[ P = \frac{1}{3} \rho v_{rms}^2 \] where \(\rho\) is the density of the gas. ### Step 3: Calculate Density Density (\(\rho\)) can be expressed in terms of the number of molecules (N) and the mass of each molecule (m): \[ \rho = \frac{N \cdot m}{V} \] ### Step 4: Substitute Density into the Pressure Equation Substituting the expression for density into the pressure equation gives: \[ P = \frac{1}{3} \left(\frac{N \cdot m}{V}\right) v_{rms}^2 \] ### Step 5: Rearrange to Solve for N Rearranging the equation to solve for N: \[ N = \frac{3PV}{m v_{rms}^2} \] ### Step 6: Substitute the Values Now, substitute the known values into the equation: - P = \(10^5\) Pa - V = \(10^{-4}\) m³ - m = \(4.556 \times 10^{-25}\) kg - \(v_{rms} = 350\) m/s So, \[ N = \frac{3 \times (10^5) \times (10^{-4})}{(4.556 \times 10^{-25}) \times (350^2)} \] ### Step 7: Calculate the Denominator First, calculate \(350^2\): \[ 350^2 = 122500 \] Now, calculate the denominator: \[ (4.556 \times 10^{-25}) \times 122500 = 5.5707 \times 10^{-20} \] ### Step 8: Calculate N Now substitute back into the equation for N: \[ N = \frac{3 \times 10^5 \times 10^{-4}}{5.5707 \times 10^{-20}} \] \[ N = \frac{3 \times 10^{1}}{5.5707 \times 10^{-20}} \] \[ N = \frac{3}{5.5707} \times 10^{21} \] \[ N \approx 5.39 \times 10^{21} \] ### Step 9: Round the Result Rounding gives: \[ N \approx 5.4 \times 10^{21} \] ### Final Answer The number of molecules in 100 cc of gas at NTP is approximately: \[ \boxed{5.4 \times 10^{21}} \]
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