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The R.M.S. velocity of the molecules in ...

The R.M.S. velocity of the molecules in a gas at 27 °C is 300 m/s. The R.M.S. velocity of the molecules in the same gas at 927 °C is

A

1200 m/s

B

600 m/s

C

150 m/s

D

75 m/s

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The correct Answer is:
To solve the problem, we need to find the root mean square (R.M.S.) velocity of the gas molecules at a temperature of 927 °C, given that the R.M.S. velocity at 27 °C is 300 m/s. ### Step-by-Step Solution: 1. **Convert Temperatures to Kelvin**: - The temperature in Kelvin is calculated by adding 273 to the Celsius temperature. - For 27 °C: \[ T_1 = 27 + 273 = 300 \, \text{K} \] - For 927 °C: \[ T_2 = 927 + 273 = 1200 \, \text{K} \] 2. **Use the R.M.S. Velocity Formula**: - The R.M.S. velocity (\(V_{rms}\)) of gas molecules is given by the formula: \[ V_{rms} = \sqrt{\frac{3RT}{M}} \] - Where \(R\) is the gas constant, \(T\) is the temperature in Kelvin, and \(M\) is the molar mass of the gas. 3. **Set Up the Ratio of R.M.S. Velocities**: - Since we are dealing with the same gas, the molar mass \(M\) remains constant. Therefore, we can set up the ratio of the R.M.S. velocities at two different temperatures: \[ \frac{V_{rms2}}{V_{rms1}} = \sqrt{\frac{T_2}{T_1}} \] 4. **Substitute Known Values**: - We know \(V_{rms1} = 300 \, \text{m/s}\), \(T_1 = 300 \, \text{K}\), and \(T_2 = 1200 \, \text{K}\). - Plugging these values into the equation gives: \[ V_{rms2} = V_{rms1} \times \sqrt{\frac{T_2}{T_1}} = 300 \times \sqrt{\frac{1200}{300}} \] 5. **Calculate the Square Root**: - Simplifying \(\frac{1200}{300}\) gives: \[ \frac{1200}{300} = 4 \] - Therefore: \[ \sqrt{4} = 2 \] 6. **Final Calculation**: - Now substituting back: \[ V_{rms2} = 300 \times 2 = 600 \, \text{m/s} \] ### Conclusion: The R.M.S. velocity of the molecules in the gas at 927 °C is **600 m/s**.
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